Organoelement chemistry: Promising growth areas and challenges

GA Abakumov, AV Piskunov… - Russian Chemical …, 2018 - iopscience.iop.org
The chemistry of organoelement compounds is now one of the most rapidly developing
fields of research, regarding both fundamental science and solution of applied problems …

[PDF][PDF] Direct synthesis of alkoxysilanes: current state, challenges and prospects

MN Temnikov, IN Krizhanovskiy, AA Anisimov… - Russ. Chem …, 2023 - researchgate.net
The practical application of silicones is over 80 years old. Today, it would be easier to
indicate areas in which silicones are not used. Silicone applications include aircraft and …

Mechanochemistry–a new powerful green approach to the direct synthesis of alkoxysilanes

MN Temnikov, AA Anisimov, PV Zhemchugov… - Green …, 2018 - pubs.rsc.org
The present work shows a new one-stage mechanochemical method for the direct synthesis
of alkoxysilanes by silicon mechanoactivation followed by a reaction with an alcohol …

Перспективные точки роста и вызовы элементоорганической химии

ГА Абакумов, АВ Пискунов, ВК Черкасов… - Успехи химии, 2018 - mathnet.ru
Химия элементоорганических соединений в настоящее время—одна из самых
динамично развивающихся научных областей как в плане фундаментальных …

Hydrolytic polycondensation of diethoxymethylsilane under pressure

AA Kalinina, TA Pryakhina, EV Talalaeva… - Russian Chemical …, 2022 - Springer
The process of hydrolytic polycondensation of diethoxymethylsilane in water under pressure
was investigated without the use of organic solvents in non-catalytic conditions and in …

Polycondensation of diethoxydimethylsilane in active medium

A Kalinina, N Strizhiver, N Vasilenko, N Perov… - Silicon, 2015 - Springer
Polycondensation of diethoxydimethylsilane (DEDMS) in an active medium containing an
excess of acetic acid was studied. It has been shown that the process selectivity could be …

Organosilicon compounds in supercritical carbon dioxide: Synthesis, polymerization, modification, and production of new materials

MA Pigaleva, IV Elmanovich, MN Temnikov… - Polymer Science Series …, 2016 - Springer
The main promising opportunities for the advantageous combination of organosilicon
compounds and supercritical carbon dioxide both as a solvent and as a reagent in chemical …

Multifunctional hydrophobic coatings based on siloxane polymers with branched perfluoroalkyl substituents: Fast, simple and ecologically safe synthesis in active …

FV Drozdov, AL Krapivko, GV Cherkaev… - Journal of …, 2020 - Elsevier
This article discusses the synthesis of polyorganosiloxanes with 1, 1, 1, 2, 2, 3, 3-heptafluoro-
4, 4-bis (trifluoromethyl) pentyl (R f= CF 3 CF 2 CF 2 C (CF 3) 2 (CH 2) 3-) perfluoroalkyl …

Synthesis of dimethylcyclosiloxanes in the active medium

AA Kalinina, EV Talalaeva, AI Demchenko… - Russian Chemical …, 2016 - Springer
The process of condensation of dimethyldiethoxysilane in the active medium in a presence
of acetyl chloride, trifluoroacetic acid, and sulfocationites has been investigated. Their …

New approaches in silicon production and recycling for sustainable future

AM Muzafarov, AV Bystrova… - Russian Chemical …, 2013 - iopscience.iop.org
Key prerequisites for the accelerated development of chemistry of silicones are considered
in the context of the significance of organosilicon polymers for sustainable future. The …