Synthesis of indoles: recent advances

DI Bugaenko, AV Karchava… - Russian Chemical …, 2019 - iopscience.iop.org
Published data of the last 10 years concerning the development of new and upgrading of
known approaches to indole synthesis are integrated and analyzed. Modern versions of the …

Intramolecular Cyclization of the ortho‐Substituted N‐arylquinone Imines under Basic and Thermal Conditions

ES Khodykina, DV Steglenko, EV Vetrova… - …, 2023 - Wiley Online Library
Abstract The S (O, N)‐benzyl ethers of N‐arylquinone imines undergo cyclization under the
action of bases to form products of the benzothiazol, benzoxazole, and benzimidazole …

A facile approach to the synthesis of 3,4-dihydro-2H-benzo[4,5]imidazo[2,1-b][1,3,4]thiadiazines

E Khodykina, D Pobedinskaya, I Borodkina… - Journal of Sulfur …, 2024 - Taylor & Francis
An efficient approach to the synthesis of novel 2, 3-diaryl-3, 4-dihydro-2 H-benzo [4, 5]
imidazo [2, 1-b][1, 3, 4] thiadiazines via a base-catalyzed intramolecular cyclization of 2 …

Synthesis of spiro[indole-3,3′-[1,3,4]thiadiazino[3,2-a]benzimidazoles] and spiro[indole-3,6′-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazines]

NI Gaponenko, AA Kolodina, AV Lesin… - Russian Chemical …, 2010 - Springer
A method for annulation of the tetrahydrothiadiazine ring to benzimidazoles and 1, 2, 4-tri-
azoles was developed. A number of earlier unknown [1, 3, 4] thiadiazino [3, 2-a] …

6,7‐Dihydro‐5H‐1,2,4‐triazolo[3,4‐b][1,3,4]thiadiazine Ring Cleavage and Tautomerism of the Products: Experimental and Theoretical Study

AA Kolodina, AA Tsaturyan, MS Galkina… - …, 2020 - Wiley Online Library
Electronic effects of aryl substituents at the C (7)‐atom play a crucial role in the cleavage of a
six‐membered ring of 6, 7‐dihydro‐5H‐[1, 2, 4] triazolo [3, 4‐b][1, 3, 4] thiadiazines. Our …

Recent progress in the synthetic routes to triazolothiadiazines

BF Abdel-Wahab, I Althagafi - … , Sulfur, and Silicon and the Related …, 2014 - Taylor & Francis
Full article: Recent Progress in the Synthetic Routes to Triazolothiadiazines Skip to Main
Content Taylor and Francis Online homepage Taylor and Francis Online homepage Log in …

The different modes of chiral [1, 2, 3] triazolo [5, 1-b][1, 3, 4] thiadiazines: Crystal packing, conformation investigation and cellular activity

KL Obydennov, TA Kalinina, OA Vysokova… - … Section C: Structural …, 2020 - journals.iucr.org
The crystal structures of four new chiral [1, 2, 3] triazolo [5, 1-b][1, 3, 4] thiadiazines are
described, namely, ethyl 5′-benzoyl-5′ H, 7′ H-spiro [cyclohexane-1, 6′-[1, 2, 3] …

Unusual cyclization of N-imidazolyl quinone imines with the formation of thiadiazole ring and its subsequent recyclization

AA Kolodina, DV Steglenko, ES Khodykina… - Mendeleev …, 2022 - Elsevier
Di-tert-butyl-4-{[2-(2-aryl-2-oxoethylthio)-1H-imidazol-1-yl] imino} cyclohexa-2, 5-dien-1-
ones under the action of bases give products of the 2, 3-dihydroimidazo [2, 1-b] thiazol-3-ol …

Intramolecular cyclization of S-alkyl derivatives of aminomercaptoimidazoles and -benzimidazoles as a method for the annulation of the thiadiazine ring

NI Gaponenko, AA Kolodina, AV Lesin… - Russian Chemical …, 2012 - Springer
A method was developed for the annulation of the tetrahydrothiadiazine moiety to the
imidazole and benzimidazole rings through intramolecular cyclization of S-alkyl derivatives …

First example of the synthesis of indoles on a heterocyclic matrix

OV Serdyuk, VT Abaev, AA Kolodina… - Chemistry of Heterocyclic …, 2011 - Springer
We have previously reported [1, 2] the formation of a thiadiazine derivative of type 4 from 4-
amino-3-mercapto-4H-triazole 1 and its subsequent transformation with cleavage of the CS …