Confining atomically precise nanoclusters in metal–organic frameworks for advanced catalysis

YM Li, J Hu, M Zhu - Coordination Chemistry Reviews, 2023 - Elsevier
Combining metal nanoclusters (NCs) with functional supports provides excellent potential
for exploring the host–guest interactions and rational design of highly active NC-based …

Immobilization of Gold Nanoparticles on Postsynthetically Modified NU-1000 for Hydrogen Evolution Reaction

S Muhamed, RK Aparna, A Karmakar… - Inorganic …, 2023 - ACS Publications
NU-1000, being a hydrothermally stable metal–organic framework (MOF), with structural
robustness is viable for functionalization with various entities. A postsynthetic modification …

Stability and Dynamics of Zeolite-Confined Gold Nanoclusters

S Sonti, C Sun, Z Chen, RM Kowalski… - Journal of Chemical …, 2024 - ACS Publications
Nanoengineered metal@ zeolite materials have recently emerged as a promising class of
catalysts for several industrially relevant reactions. These materials, which consist of small …

Microalgal nanobiotechnology for biosynthesis of metallic NPs: In-depth into the strategies, mechanism and nanofluidic hydrodynamics

D Deb, A Sutradhar - Biocatalysis and Agricultural Biotechnology, 2024 - Elsevier
A revolutionary method called 'nanotechnology'is used to develop and use materials at the
nanoscale. Although researches in this field have gained significant impetus over the years …

Thermally Promoted Cation Exchange at the Solid State in the Transmission Electron Microscope: How It Actually Works

A Casu, M Lopez, C Melis, D Deiana, H Li, L Colombo… - ACS …, 2023 - ACS Publications
Cation exchange offers a strong postsynthetic tool for nanoparticles that are unachievable
via direct synthesis, but its velocity makes observing the onset of the reaction in the liquid …

Ethane Oxidative Dehydrogenation over Pt-Rare Earth Intermetallic Compounds with CO2 as Soft Oxidant

M Numan, A Sudalai, C Jo, SE Park - Industrial & Engineering …, 2023 - ACS Publications
Intermetallic Pt-M (M= La, Y, and Sc) nanoparticles supported on zeolite nanosponge (ZNS)
were synthesized and investigated for ethane oxidative dehydrogenation (EOD) with CO2 as …

Mercaptoamine‐assisted Post‐encapsulation of Metal Nanoparticles within Preformed Zeolites and their Analogues for Hydroisomerization and Methane …

M Song, E Eom, JW Shin, HS Cho… - Angewandte Chemie …, 2023 - Wiley Online Library
We report a general synthetic strategy for post‐encapsulation of metal nanoparticles within
preformed zeolites using post‐synthetic modification. Both anionic and cationic precursors to …

Promoting hydrogenation without side reactions over Pd nanoparticles uniformly dispersed in MFI zeolite

J Lee, E Lee, HS Lee, H Kim, YW Lee… - Chemical Engineering …, 2023 - Elsevier
Zeolites have been widely applied as support materials for metal nanoparticles. However,
when developing a metal/zeolite catalyst for hydrogenation reactions, the Brønsted acid …

Manipulation of chemical behavior of species by a temperature-program strategy: efficiently confining metal oxide nanoclusters in a hollow zeolite

Y Zhai, K Wang, M Sun, F Wang, X Zhang… - Journal of Materials …, 2023 - pubs.rsc.org
Currently, the development of a green strategy based on novel confinement theory to guide
the limitation of metal particles encapsulated in zeolite to nano-size at a high amount of …

Opposite trends in acetylene/ethylene selectivity change after organic functionalization of Na+-and Cs+-MOR zeolites

TH Kim, P Kang, E Eom, SK Lee, JC Kim… - Separation and …, 2025 - Elsevier
We developed a novel adsorbent with significant adsorption capacity and selectivity for
acetylene (C 2 H 2) in an acetylene/ethylene (C 2 H 2/C 2 H 4) mixture, through post …