Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …

Chiral metal–organic frameworks (CMOFs) are a major part of chiral inorganic–organic
hybrid materials that lead to considerable attention of researchers, especially in recent …

The search for versatile heterogeneous catalysts with multiple active sites for broad
asymmetric transformations has long been of great interest, but it remains a formidable …

In this work, we demonstrate cooperative asymmetric catalysis by a metal–organic
framework (MOF) as exemplified in the context of catalyzing cyanation of aldehydes with a …

Salen-type ligands have been used extensively to stabilize metals for homogeneous
catalysis. It has been demonstrated that the marriage of complexes of salen with porous …

Pump it up! The sluggish reactivity of organozinc reagents in additions to aldehydes,
ketones, and CO 2 can be increased by MgCl 2, which is usually generated in the …

The ligands N, N′-bis (3-tert-butyl-5-methoxysalicylidene)-1, 2-ethanediamine and N, N′-
bis (3-tert-butyl-5-methoxysalicylidene)-1, 3-propanediamine were chelated to V (IV)═ O (1 …

Two chiral porous metal–organic frameworks (MOFs) were constructed from [VO (salen)]‐
derived dicarboxylate and dipyridine bridging ligands. After oxidation of VIV to VV, they were …

We demonstrate that well-known transition metal catalysts can be transformed into high-
performance versions by the simple use of a fluoride anion source. In situ fluoride-activated …

A chiral porous metal–organic framework (MOF) decorated with radicals has been
successfully constructed by cocrystallizing achiral (2, 2, 6, 6-tetramethylpiperidin-1-yl) oxyl …