Visible‐Light‐Mediated C‐2 Functionalization and Deoxygenative Strategies in Heterocyclic N‐Oxides

J Singh, RI Patel, A Sharma - Advanced Synthesis & Catalysis, 2022 - Wiley Online Library
Heterocyclic N‐oxides are prevalent in numerous natural products with broad applications in
pharmaceuticals, agrochemicals, material sciences, and asymmetric synthesis. Owing to …

Diaryliodoniums Salts as Coupling Partners for Transition-Metal Catalyzed C- and N-Arylation of Heteroarenes

A Pacheco-Benichou, T Besson, C Fruit - Catalysts, 2020 - mdpi.com
Owing to the pioneering works performed on the metal-catalyzed sp2 C–H arylation of
indole and pyrrole by Sanford and Gaunt, N–and C-arylation involving diaryliodonium salts …

Cp*IrIII-Catalyzed C8-Selective C–H Activation Enables Room-Temperature Direct Arylation of Quinoline N-Oxides with Arylsilanes

H Tian, T Hou, X Yang, H Xu… - The Journal of Organic …, 2023 - ACS Publications
The Cp* Ir-catalyzed C8-selective arylation of quinoline N-oxides with arylsilanes is
developed. This C–H activation transformation can be carried out under mild reaction …

Palladium-Catalysed Intermolecular Direct C–H Bond Arylation of Heteroarenes with Reagents Alternative to Aryl Halides: Current State of the Art

R Rossi, M Ciofalo - Current Organic Chemistry, 2022 - ingentaconnect.com
This unprecedented review with 322 references provides a critical up-to-date picture of the
Pd-catalysed intermolecular direct C–H bond arylation of heteroarenes with arylating …

Diaryliodonium Salts in Transition‐Metal‐Catalyzed Chelation‐Induced C(sp2/sp3)−H Arylations

A Joshi, SR De - European Journal of Organic Chemistry, 2021 - Wiley Online Library
Transition‐metal‐catalyzed Cross‐coupling via directing group assisted C− H bond
activation has become an expedient tool in current synthesis to achieve diverse molecular …

Palladium-Catalyzed Regioselective C-Arylation and C, N-Diarylation of N-Aryl-2, 3-dihydrophthalazine-1, 4-diones Using Diaryliodonium Salts

S Naharwal, ND Kharat, CK Mahesha, K Bajaj… - …, 2023 - thieme-connect.com
Regioselective C-arylation and C, N-diarylation in 2-aryl-2, 3-dihydrophthalazine-1, 4-
diones has been successfully accomplished with diaryliodonium salts under base-mediated …

Rh-Catalyzed Functionalization of N-Heterocycles Through C–H Activation

S Kumar, V Kanchupalli - 2024 - Springer
N-heterocycles are important motifs in nature, not only because of their abundance but also
because of their chemical and biological significance. In fact, approximately 70% of natural …

Six-membered ring systems: pyridines and benzo derivatives

JC Badenock - Progress in Heterocyclic Chemistry, 2021 - Elsevier
Pyridines and their benzo derivatives are versatile organic scaffolds celebrated for their
presence in a variety of agrochemicals, polymers, and pharmaceuticals. Accordingly, the …