Brought to life more than half a century ago and successfully applied for high-value
petrochemical intermediates production, nickel-catalyzed olefin oligomerization is still a very …

The transformation of ethylene and alkenes is of high importance for the chemical industry.
In this review, we focus on selective alkenes transformation where metallacyclopentane is …

The reduced availability of propylene and C4 products from steam crackers continues to
provoke on-purpose technologies for light olefins such that almost 30% of propylene in 2025 …

We report the dimerization and oligomerization of ethylene using bis (phosphino) boryl
supported Ni (II) complexes as catalyst precursors. By using alkylaluminum (III) compounds …

Metallacyclopentanes are important reaction intermediates for catalytic processes, such as
selective ethylene oligomerization and diene cyclooligomerization. Reactions of …

A series of catalysts, NiSO4/γ-Al2O3, for ethylene dimerization were prepared by the
impregnation method using an aqueous solution of nickel sulfate. Nickel sulfate supported …

Nickel sulfate supported on γ-Al2O3 was found to be very active even at room temperature,
giving a maximum in both activity and acidity when catalyst containing 20% NiSO4 was …

Abstract A NiSO 4/Re 2 O 7/γ-Al 2 O 3 catalyst was prepared by co-impregnation using an
aqueous solution of NiSO 4 and [NH 4][ReO 4], which catalyzes direct conversion of ethene …

Mechanistic studies have been performed for the recently developed, Ni‐catalysed selective
cross‐coupling reaction between aryl and alkyl aldehydes. A mono‐carbonyl activation …

The Cossee–Arlman mechanism of nickel-catalyzed oligomerization and dimerization with
various N∩ N-type ligands was studied using the DFT method. For the L1 ligands (L1= 2, 9 …