Optimization of catalysts and conditions in gold (I) catalysis—counterion and additive effects

Z Lu, T Li, SR Mudshinge, B Xu… - Chemical …, 2021 - ACS Publications
Gold catalysis has proven to be an important breakthrough for organic synthesis. The
tunable nature of gold catalysts, the unique properties of gold, and the mild reaction …

Late transition metal-catalyzed hydroamination and hydroamidation

L Huang, M Arndt, K Gooßen, H Heydt… - Chemical …, 2015 - ACS Publications
This Review examines recent developments in late transition metal-catalyzed
hydroamination and-amidation reactions. A hydroamination is a reaction in which an N− H …

Supramolecular catalysis. Part 1: non-covalent interactions as a tool for building and modifying homogeneous catalysts

M Raynal, P Ballester, A Vidal-Ferran… - Chemical Society …, 2014 - pubs.rsc.org
Supramolecular catalysis is a rapidly expanding discipline which has benefited from the
development of both homogeneous catalysis and supramolecular chemistry. The properties …

Counterion effects in homogeneous gold catalysis

M Jia, M Bandini - Acs Catalysis, 2015 - ACS Publications
Homogeneous gold catalysis has received growing attention over the past few years,
enabling the replacement of consolidated organic reactions with more simple, selective, and …

Intriguing mechanistic labyrinths in gold (I) catalysis

C Obradors, AM Echavarren - Chemical Communications, 2014 - pubs.rsc.org
Many mechanistically intriguing reactions have been developed in the last decade using
gold (I) as catalyst. Here we review the main mechanistic proposals in gold-catalysed …

Anatomy of gold catalysts: facts and myths

B Ranieri, I Escofet, AM Echavarren - Organic & Biomolecular …, 2015 - pubs.rsc.org
Anatomy of gold catalysts: facts and myths - Organic & Biomolecular Chemistry (RSC Publishing)
DOI:10.1039/C5OB00736D Royal Society of Chemistry View PDF VersionPrevious ArticleNext …

One-point binding ligands for asymmetric gold catalysis: phosphoramidites with a TADDOL-related but acyclic backbone

H Teller, M Corbet, L Mantilli… - Journal of the …, 2012 - ACS Publications
Readily available phosphoramidites incorporating TADDOL-related diols with an acyclic
backbone turned out to be excellent ligands for asymmetric gold catalysis, allowing a …

Allenes and computational chemistry: from bonding situations to reaction mechanisms

E Soriano, I Fernández - Chemical Society Reviews, 2014 - pubs.rsc.org
The present review is focused on the application of computational/theoretical methods to the
wide and rich chemistry of allenes. Special emphasis is made on the interplay and synergy …

[HTML][HTML] Gold (I)-catalyzed stereoconvergent, intermolecular enantioselective hydroamination of allenes

KL Butler, M Tragni, RA Widenhoefer - … Chemie (International ed. in …, 2012 - ncbi.nlm.nih.gov
Abstract A 1: 2 mixture of [(S)-2](AuCl) 2 [(S)-2=(S)-3, 5-t-Bu-4-MeO-MeOBIPHEP] and
AgBF4 catalyzes the stereoconvergent, intermolecular enantioselective hydroamination of …

Counterion effect in the reaction mechanism of NHC gold (I)-catalyzed alkoxylation of alkynes: computational insight into experiment

G Ciancaleoni, L Belpassi, D Zuccaccia… - Acs …, 2015 - ACS Publications
Experimental data suggest that anions that provide a compromise between the hydrogen-
bond acceptor and the coordinating powers rather than poor coordinating anions …