Radical aryl migration reactions are of particular interest to the chemical community due to
their potential application in radical chemistry and organic synthesis. The neophyl …

Since the first report of a radical aryl migration reaction by Wieland in 1911, many examples
have appeared in the literature. 1 The most extensively investigated aryl migration reaction …

A copper-catalyzed radical acyl-cyanation of alkenes with aldehydes, employing TBHP as
an initiator, has been developed and is reported in this study. Mechanistic studies support …

In recent years, powerful new methods for the generation of alkoxyl radicals under mild and
neutral conditions have been developed. This progress has led to a thorough investigation …

Stereoelectronic restrictions on homoallylic ring expansion in alkyne cascades can be
overcome by using alkenes as synthetic equivalents of alkynes in reaction cascades that are …

A variety of fragmentations and rearrangements can follow Bergman cyclization in
enediynes equipped with acetal rings mimicking the carbohydrate moiety of natural …

We report a metal-free procedure for transformation of phenols into esters and amides of
benzoic acids via a new radical cascade. Diaryl thiocarbonates and thiocarbamates …

Direct evidence for the formation of alkoxy radicals is reported in radical cascades using
traceless directing groups. Despite the possibility of hydrogen abstraction in the fragmenting …

A product and time-resolved kinetic study of the effect of ring substitution on the reactivity of
1, 1-diarylalkoxyl radicals has been carried out. The radicals undergo an O-neophyl shift to …

A series of hitherto unknown N‐(pent‐4‐enyl‐1‐oxy) pyridine‐2 (1 H)‐thiones (6) were
prepared from substituted pent‐4‐enyl tosylates or benzylic chlorides. On irradiation with …