Progressive study on ruthenium catalysis for de (hydrogenative) alkylation and alkenylation using alcohols as a sustainable source

R Sharma, A Samanta, B Sardar, M Roy… - Organic & Biomolecular …, 2022 - pubs.rsc.org
At present, alcohols are considered sustainable starting materials that can be used in
organic synthesis for various organic transformations and the preparation of commodity …

Ru-catalyzed selective catalytic methylation and methylenation reaction employing methanol as the C1 source

N Biswas, D Srimani - The Journal of Organic Chemistry, 2021 - ACS Publications
Methanol can be employed as a green and sustainable methylating agent to form C–C and
C–N bonds via borrowing hydrogen (BH) methodology. Herein we explored the activity of …

Reaction condition controlled nickel (ii)-catalyzed C–C cross-coupling of alcohols

MJ Zhang, HX Li, DJ Young, HY Li… - Organic & Biomolecular …, 2019 - pubs.rsc.org
The challenge in the C–C cross-coupling of secondary and primary alcohols using
acceptorless dehydrogenation coupling (ADC) is the difficulty in accurately controlling …

Manganese‐catalyzed Dual‐deoxygenative Coupling of Primary Alcohols with 2‐arylethanols

Y Wang, Z Shao, K Zhang, Q Liu - Angewandte Chemie, 2018 - Wiley Online Library
Reported herein is a general and efficient dual‐deoxygenative coupling of primary alcohols
with 2‐arylethanols catalyzed by a well‐defined Mn/PNP pincer complex. This reaction is the …

Dearomatization‐Rearomatization Strategy for ortho‐Selective Alkylation of Phenols with Primary Alcohols

J Yu, CJ Li, H Zeng - Angewandte Chemie International Edition, 2021 - Wiley Online Library
Phenols are common precursors and core structures of a variety of industrial chemicals
ranging from pharmaceuticals to polymers. However, the synthesis of site‐specifically …

CO2-Promoted and Copper-Catalyzed Dehydroxylative Coupling of Benzylic Alcohols by the NaBH4/I2 System

Z Guo, B Yang, T Pang, X Wei - The Journal of Organic Chemistry, 2024 - ACS Publications
An efficient and CO2-promoted dehydroxylative coupling of benzylic alcohols catalyzed by
ligand-free cuprous chloride has been achieved. The discovered catalytic reductive coupling …

Pincer-Ruthenium-Catalyzed Direct Formation of Fuel-Grade Alkanes via a Net-Decarboxylative Coupling of Alcohols

PG Nandi, P Maity, A Kumar - ACS Catalysis, 2024 - ACS Publications
The net-decarboxylative coupling of low-molecular weight alcohols to high-molecular weight
alkanes has been investigated using a series of NNN pincer-Ru catalysts based on bis …

Ru-catalyzed cross-dehydrogenative coupling between primary alcohols to guerbet alcohol derivatives: With relevance for fragrance synthesis

S Manojveer, S Salahi, OF Wendt… - The Journal of Organic …, 2018 - ACS Publications
A simple method has been developed for the cross dehydrogenative coupling between two
different primary alcohols using readily available RuCl2 (PPh3) 3 as a precatalyst through …

Recent advancements on decarbonylation reactions assisted by Ru-complexes: Synthetic and mechanistic approach

SA Patra, R Dinda, PD Pattanayak, D Mohapatra - Dalton Transactions, 2022 - pubs.rsc.org
This frontier article covers the recent advancements in ruthenium complex catalysed
decarbonylation reactions of different types of carbonyl compounds and provides a direction …

Manganese-catalyzed dehydrogenative/deoxygenative coupling of alcohols

Y Wang, Q Liu - Synlett, 2020 - thieme-connect.com
Valorization of biomass has become an area of intense focus because of the diminishing
reserves of crude oil and the ongoing problem of climate change. The principal strategies for …