Superacid chemistry

GA Olah, GKS Prakash, J Sommer, A Molnar - 2009 - books.google.com
The chemistry of superacids has developed in the last two decades into a field of growing
interest and importance. Now available in a new expanded second edition, this definitive …

Ynamide Smiles rearrangement triggered by visible-light-mediated regioselective ketyl–ynamide coupling: rapid access to functionalized indoles and isoquinolines

ZS Wang, YB Chen, HW Zhang, Z Sun… - Journal of the …, 2020 - ACS Publications
In the past decades, significant advances have been made on radical Smiles
rearrangement. However, the eventually formed radical intermediates in these reactions are …

Synthesis of hyperbranched polymers with controlled structure

Y Segawa, T Higashihara, M Ueda - Polymer Chemistry, 2013 - pubs.rsc.org
Hyperbranched polymers (HBPs) are highly branched macromolecules with 3-dimensional
globular structures, which have unique properties, such as low viscosity, high solubility, and …

[HTML][HTML] High-performance imidazole-containing polymers for applications in high temperature polymer electrolyte membrane fuel cells

T Mu, L Wang, Q Wang, Y Wu, P Jannasch… - Journal of Energy …, 2024 - Elsevier
This work focuses on the development of high temperature polymer electrolyte membranes
(HT-PEMs) as key materials for HT-PEM fuel cells (HT-PEMFCs). Recognizing the …

Alkaline polymers of intrinsic microporosity: high-conduction and low-loss anhydrous proton exchange membranes for energy conversion

S Zhou, J Guan, Z Li, L Huang, J Zheng, S Li… - Journal of Materials …, 2021 - pubs.rsc.org
The development of anhydrous high-temperature proton-exchange membranes (HT-PEMs)
combining durable high proton conductivity and modest mechanical properties is a huge …

N-sulfonated poly (arylene-oxindole) for vanadium redox flow battery applications

PP Bavdane, S Sreenath, DY Nikumbe… - ACS Applied Energy …, 2022 - ACS Publications
We describe the synthesis of N-sulfonated poly (arylene-oxindole) by metal-free superacid,
denoted IDB, IBP, and IFP by polycondensation of isatin with 1, 4-diphenoxybenzene …

Superacid-Catalyzed Reactions of Cinnamic Acids and the Role of Superelectrophiles1

Rendy, Y Zhang, A McElrea, A Gomez… - The Journal of Organic …, 2004 - ACS Publications
The chemistry of cinnamic acids and related compounds has been studied. In superacid-
catalyzed reactions with arenes, two competing reaction mechanisms are proposed. Both …

Well-defined, linear, wholly aromatic polymers with controlled content and position of pyridine moieties in macromolecules from one-pot, room temperature, metal-free …

E Cetina-Mancilla, LI Olvera, J Balmaseda… - Polymer …, 2020 - pubs.rsc.org
Synthesis of processable, aromatic pyridine-containing polymers has always been a great
challenge. Here, we report for the first time a robust, low-cost synthesis of well defined, high …

Superelectrophiles and the effects of trifluoromethyl substituents

MJ O'Connor, KN Boblak, MJ Topinka… - Journal of the …, 2010 - ACS Publications
Trifluoromethyl-substituted superelectrophiles were generated in superacid (CF3SO3H),
and their chemistry was examined. The strong electron-withdrawing properties of the …

Iodine (i) complexes incorporating sterically bulky 2-substituted pyridines

JS Ward, RM Gomila, A Frontera, K Rissanen - RSC advances, 2022 - pubs.rsc.org
The silver (I) and iodine (I) complexes of the 2-substituted pyridines 2-(diphenylmethyl)
pyridine (1) and 2-(1, 1-diphenylethyl) pyridine (2), along with their potential protonated side …