Synthesis, structure, and zero-field SMM behavior of homometallic Dy2, Dy4, and Dy6 complexes
The synthesis, structure, and magnetic properties of three DyIII complexes of different
nuclearity,[Dy2 (H2L) 2 (NO3)][NO3]· 2H2O· CH3OH (1),[Dy4 (HL) 2 (piv) 4 (OH) 2](2), and …
nuclearity,[Dy2 (H2L) 2 (NO3)][NO3]· 2H2O· CH3OH (1),[Dy4 (HL) 2 (piv) 4 (OH) 2](2), and …
Self-Assembled Lanthanide Phosphinate Square Grids (Ln = Er, Dy, and Tb): Dy4 Shows SMM/SMT and Tb4 SMT Behavior
Tetranuclear [2× 2] square-grid-like LnIII clusters have been synthesized by reacting LnCl3·
6H2O salts with bis [α-hydroxy (p-bromophenyl) methyl] phosphinic acid [R2PO2H, where …
6H2O salts with bis [α-hydroxy (p-bromophenyl) methyl] phosphinic acid [R2PO2H, where …
Designing a Dy2 Single-Molecule Magnet with Two Well-Differentiated Relaxation Processes by Using a Nonsymmetric Bis-bidentate Bipyrimidine-N-Oxide Ligand …
Herein we report a dinuclear [(μ-mbpymNO){(tmh) 3Dy} 2](1) single-molecule magnet (SMM)
showing two nonequivalent DyIII centers, which was rationally prepared from the reaction of …
showing two nonequivalent DyIII centers, which was rationally prepared from the reaction of …
3D isomorphous lanthanide coordination polymers displaying magnetic refrigeration, slow magnetic relaxation and tunable proton conduction
Four new isostructural lanthanide-based three-dimensional (3D) coordination polymers
(CPs),{[Ln4 (OH) 4 (L) 2 (H2O) 8]· 4.6 H2O· 1.4 CH3CN} n (Ln3+= Gd3+ (1), Dy3+ (2), Ho3+ …
(CPs),{[Ln4 (OH) 4 (L) 2 (H2O) 8]· 4.6 H2O· 1.4 CH3CN} n (Ln3+= Gd3+ (1), Dy3+ (2), Ho3+ …
Three Isostructural One-Dimensional LnIII Chains with Distorted Cubane Motifs Showing Dual Fluorescence and Slow Magnetic Relaxation/Magnetocaloric Effect
Y Li, JW Yu, ZY Liu, EC Yang, XJ Zhao - Inorganic Chemistry, 2015 - ACS Publications
Three new homometallic lanthanide complexes with mixed carboxylate-modified rigid
ligands,[Ln (μ3-OH)(na)(pyzc)] n (na–= 1-naphtholate, pyzc–= 2-pyrazinecarboxylate, Ln …
ligands,[Ln (μ3-OH)(na)(pyzc)] n (na–= 1-naphtholate, pyzc–= 2-pyrazinecarboxylate, Ln …
Homodinuclear lanthanide {Ln 2}(Ln= Gd, Tb, Dy, Eu) complexes prepared from an o-vanillin based ligand: luminescence and single-molecule magnetism behavior
Four dinuclear lanthanide complexes [Gd2 (H2L) 2 (µ-piv) 2 (piv) 2]· 2CHCl3 (1),[Tb2 (H2L)
2 (µ-piv) 2 (piv) 2]· 2CHCl3 (2),[Dy2 (H2L) 2 (µ-piv) 2 (piv) 2]· 2CHCl3 (3) and [Eu2 (H2L) 2 …
2 (µ-piv) 2 (piv) 2]· 2CHCl3 (2),[Dy2 (H2L) 2 (µ-piv) 2 (piv) 2]· 2CHCl3 (3) and [Eu2 (H2L) 2 …
{Mn6IIIMnIVDy2III} Single-Molecule Magnet Based on Cubane Subunits
M Darii, J van Leusen, VC Kravtsov… - Crystal Growth & …, 2023 - ACS Publications
A new mixed-valence heterometallic nonanuclear cluster [Mn7Dy2 (μ4-O) 2 (μ3-O) 4 (μ3-
OMe) 2 (μ2-OH)(piv) 8 (dea) 2 (MeOH) 2 (H2O) 2](NO3)· H2O (1)(where Hpiv= pivalic acid) …
OMe) 2 (μ2-OH)(piv) 8 (dea) 2 (MeOH) 2 (H2O) 2](NO3)· H2O (1)(where Hpiv= pivalic acid) …
Cycloheptatrienyl trianion: an elusive bridge in the search of exchange coupled dinuclear organolanthanide single-molecule magnets
The preparation of η-cyclopentadienyl (η5-C5R5), η-arene (η6-C6R6), and η-
cyclooctatetraenyl (η8-C8R8) bridging motifs are common in organometallic chemistry; …
cyclooctatetraenyl (η8-C8R8) bridging motifs are common in organometallic chemistry; …
Homometallic DyIII Complexes of Varying Nuclearity from 2 to 21: Synthesis, Structure, and Magnetism
The synthesis, structure, and magnetic properties of four DyIII coordination compounds
isolated as [Dy2 (LH2) 2 (μ2‐η1: η1‐Piv)] Cl⋅ 2 MeOH⋅ H2O (1),[Dy4 (LH) 2 (μ3‐OH) 2 …
isolated as [Dy2 (LH2) 2 (μ2‐η1: η1‐Piv)] Cl⋅ 2 MeOH⋅ H2O (1),[Dy4 (LH) 2 (μ3‐OH) 2 …
Single-Molecule-Magnet Behavior in a [2 × 2] Grid DyIII4 Cluster and a Dysprosium-Doped YIII4 Cluster
Thanks to the MeCN hydrolysis in situ reaction, a [2× 2] square grid DyIII4 cluster based on a
polypyridyl triazolate ligand,[Dy4 (OH) 2 (bpt) 4 (NO3) 4 (OAc) 2](1), was separated …
polypyridyl triazolate ligand,[Dy4 (OH) 2 (bpt) 4 (NO3) 4 (OAc) 2](1), was separated …