Thermal C–C bond cleavage reactions allow the construction of structurally diverse
molecular skeletons via predictable and efficient bond reorganizations. Visible light …

Enantioconvergent catalysis has expanded asymmetric synthesis to new methodologies
able to convert racemic compounds into a single enantiomer. This review covers recent …

Oximes are valuable synthetic building blocks with reactivity modes that enable their use in
diverse methodologies, from cycloadditions to bioconjugation. Their reactivity towards …

The photo-/electrocatalytic functionalization of quinoxalin-2 (1H)-ones has emerged as a
promising and powerful approach for post-synthetic modification of quinoxalin-2 (1H)-ones …

Visible-light photoredox catalysis is a powerful and attractive strategy for organic molecule
activation and new reaction design owing to its environmental-friendly characteristics and …

The intermolecular three-component alkene vicinal dicarbofunctionalization (DCF) reaction
allows installation of two different carbon fragments. Despite extensive investigation into its …

Recent years have witnessed a renaissance of radical cross‐coupling of cycloketone
oximes which served as active cyanoalkyl radical via ring fragmentation in various …

The creation of new bonds via CF bond cleavage of readily available per-or oligofluorinated
compounds has received growing interest. Using such a strategy, a myriad of valuable …

Oximes represent one of the fundamental organic compound classes with a wide range of
synthetic applications. In the last decade O‐substituted oximes were recognized as the …

Cyclization/functionalization of unsaturated oxime esters (ethers) is a powerful strategy for
the synthesis of versatile functionalized nitrogen-containing scaffolds, which are valuable …