Surface chemistry of transition metal carbides

HH Hwu, JG Chen - Chemical reviews, 2005 - ACS Publications
Transition metal carbides (TMCs) are produced by incorporating carbon atoms into the
interstitial sites of their parent metals, which typically include all 3d elements and 4d/5d …

Nickel molybdenum carbides: Synthesis, characterization, and catalytic activity in hydrodeoxygenation of anisole and ethyl caprate

AA Smirnov, Z Geng, SA Khromova, SG Zavarukhin… - Journal of catalysis, 2017 - Elsevier
Mo-and Ni-containing carbide catalysts were prepared by a Pechini-based method using
citric acid as a complexing agent. All the catalysts were characterized by temperature …

Carbide-forming groups IVB-VIB metals: a new territory in the periodic table for CVD growth of graphene

Z Zou, L Fu, X Song, Y Zhang, Z Liu - Nano letters, 2014 - ACS Publications
Early transition metals, especially groups IVB-VIB metals, can form stable carbides, which
are known to exhibit excellent “noble-metal-like” catalytic activities. We demonstrate herein …

Effect of heat treatment on structure and properties of molybdenum nitride and molybdenum carbonitride films prepared by magnetron sputtering

J Qian, S Li, J Pu, Z Cai, H Wang, Q Cai, P Ju - Surface and Coatings …, 2019 - Elsevier
The molybdenum nitride (MoN) film with multiphase structure (Mo 2 N, MoN and Mo) was
successfully prepared using magnetron sputtering. The mechanical and tribological …

Synthesis of β-Mo2C Thin Films

CA Wolden, A Pickerell, T Gawai, S Parks… - … applied materials & …, 2011 - ACS Publications
Thin films of stoichiometric β-Mo2C were fabricated using a two-step synthesis process.
Dense molybdenum oxide films were first deposited by plasma-enhanced chemical vapor …

Boosting the activity of transition metal carbides towards methane activation by nanostructuring

M Figueras, RA Gutiérrez, H Prats, F Viñes… - Physical Chemistry …, 2020 - pubs.rsc.org
The interaction of methane with pristine surfaces of bulk MoC and Mo2C is known to be
weak. In contrast, a series of X-ray photoelectron spectroscopy (XPS) experiments …

Effect of processing parameters on the mechanochemical synthesis of nanocrystalline molybdenum carbide

S Khabbaz, A Honarbakhsh-Raouf, A Ataie… - International Journal of …, 2013 - Elsevier
Nanocrystalline molybdenum carbide (Mo 2 C) was synthesized from commercially pure
MoO 3 and graphite using high energy planetary ball milling and subsequent heat treatment …

Diamond-like carbon coatings on a CoCrMo implant alloy: A detailed XPS analysis of the chemical states at the interface

U Müller, CV Falub, G Thorwarth, C Voisard, R Hauert - Acta materialia, 2011 - Elsevier
Low friction and wear resistant coatings have a long history of successful applications in
industry. It has long been hoped that these coatings, especially diamond-like carbon (DLC) …

Preparation and characterization of nanocrystalline composites Mo–C–N hard films

Q Liu, T Liu, QF Fang, FJ Liang, JX Wang - Thin Solid Films, 2006 - Elsevier
Molybdenum carbonitride (MoCN) films were deposited on Si (001) and stainless steel
substrates by reactive direct-current magnetron sputtering with a molybdenum and graphite …

One-pot synthesis of amorphous high entropy Mo–C–N–O–S solids with ultradispersed Mo sites

D Ryaboshapka, P Afanasiev - Journal of Materials Science, 2024 - Springer
Reaction of urea with ammonium heptamolybdate (HMA) at 550 in inert atmosphere leads to
nanocrystalline molybdenum carbide Mo 2 C, whereas reaction of HMA with elemental …