Synthesis of Iridium Tetrazolato, Triazolinato, and Triazolato Complexes by [3+ 2] Cycloaddition of Iridium (III) Azido Complexes with Unsaturated Nitriles

I Sánchez-Sordo, J Díez, E Lastra, MP Gamasa - Organometallics, 2019 - ACS Publications
The diazido complexes [Ir (η5-C5Me5)(N3) 2 (PPh3)](1a),[Ir (η5-C5Me5)(N3) 2 {κ (P)-
R2PCH2CH═ CH2}](R= Ph (1b), i Pr (1c)) have been synthesized and their [3+ 2] …

Cyclometallated iridium NHC complexes containing self-isomerised ligands as catalysts for hydrosilylation and transfer hydrogenation reactions

E van Vuuren, FP Malan, M Landman - New Journal of Chemistry, 2023 - pubs.rsc.org
Novel Ir-based NHC complexes (1–4) were synthesised using N-alkenyl functionalised
imidazolium salts with Ir (III) precursors. Complex 1 represents an unprecedented …

[HTML][HTML] Synthesis of iridaoxaphospholane complexes

N Alvarez-Pazos, AM Grana, J Bravo, M Talavera… - Polyhedron, 2023 - Elsevier
An alkenylphosphinite compound has been used to synthesize the unknown
iridaoxaphospholane complexes which have been characterized in solution and solid state …