High pressure range of the addition of HO to HO, NO, NO2, and CO. I. Saturated laser induced fluorescence measurements at 298 K

R Forster, M Frost, D Fulle, HF Hamann… - The Journal of …, 1995 - pubs.aip.org
Saturated laser induced fluorescence is used for the sensitive detection of radicals in high
pressure gases. The method and its application to a series of addition reactions of HO …

Sequential two (blue) photon absorption by NO2 in the presence of H2 as a source of OH in pulsed photolysis kinetic studies: Rate constants for reaction of OH with …

SA Carl, JN Crowley - The Journal of Physical Chemistry A, 1998 - ACS Publications
The use of the sequential two-photon dissociation of NO2 (420− 450 nm) in the presence of
H2 as a novel source of OH in kinetic studies has been assessed. Two-photon absorption by …

Temperature and pressure dependence of the addition reactions of HO to NO and to IV. Saturated laser-induced fluorescence measurements up to 1400 bar

D Fulle, HF Hamann, H Hippler, J Troe - The Journal of chemical …, 1998 - pubs.aip.org
The recombination reactions HO+ NO+ M⇒ HONO+ M (1) and HO+ NO 2+ M⇒ HNO 3+ M
(2) have been investigated over an extended pressure (1–1000 bar) and temperature (250 …

[HTML][HTML] Kinetics of the OH  reaction: effect of water vapour and new parameterization for global modelling

D Amedro, M Berasategui, AJC Bunkan… - Atmospheric …, 2020 - acp.copernicus.org
The effect of water vapour on the rate coefficient for the atmospherically important,
termolecular reaction between OH and NO 2 was determined in He–H 2 O (277, 291, and …

Ab initio study of the reaction: Prediction of the total rate constant and product branching ratios for the forward and reverse processes

RS Zhu, MC Lin - The Journal of chemical physics, 2003 - pubs.aip.org
The mechanisms for HO 2+ NO and its reverse reactions have been investigated by ab initio
molecular orbital and transition-state theory calculations. The species involved have been …

Reaction of OH+ NO 2+ M: Kinetic evidence of isomer formation

H Hippler, S Nasterlack, F Striebel - Physical Chemistry Chemical …, 2002 - pubs.rsc.org
The objective of this paper is twofold: First, we present new experimental data on the
reaction of OH+ NO2 at room temperature, which show that the results obtained earlier in …

Theoretical study of the OH+ NO2 reaction: formation of nitric acid and the hydroperoxyl radical

D Chakraborty, J Park, MC Lin - Chemical physics, 1998 - Elsevier
The reaction of OH with NO2 has been studied by high level ab initio molecular orbital and
statistical theory calculations. The potential energy surface for the association leading to the …

Kinetics of the OH  reaction: rate coefficients (217–333 K, 16–1200 mbar) and fall-off parameters for and bath gases

D Amedro, AJC Bunkan, M Berasategui… - Atmospheric …, 2019 - acp.copernicus.org
The radical terminating, termolecular reaction between OH and NO 2 exerts great influence
on the NO y/NO x ratio and O 3 formation in the atmosphere. Evaluation panels (IUPAC and …

The chemistry of the polluted troposphere

JG Calvert - Chemistry of the Unpolluted and Polluted Troposphere …, 1982 - Springer
Several important aspects of the chemistry of the polluted troposphere are discussed in
terms of the elementary reactions involved. First, the mechanism of ozone generation in the …

Characteristics of treatment of diesel flue gas by irradiation of pulsed, intense relativistic electron beam

G Imada, K Yatsui - IEEE transactions on plasma science, 2006 - ieeexplore.ieee.org
Diesel flue gas in a chamber spatially isolated from electron-beam source has been
successfully treated by pulsed, intense relativistic electron beam (PIREB). A flue gas …