Formation and detection of phosphinidenes (R P̈:) in the decomposition of
cyclophosphanes and in the reaction of dichlorophosphanes with metals are considered …

B. Semiempirical Calculations.. IV. Experimental Methods..... A. Infrared........ B.
Microwave....... C. Nuclear Magnetic Resonance. D. Racemization and Epimerization V …

A unique hexaphosphane featuring a 2, 2′-bi (1, 2, 3-triphosphacyclopentane) moiety (19)
and an ethylene-bridged bis-isotetraphosphane (27 c, m) were both selectively prepared in …

Data on the methods of synthesis and reactivities of organic diphosphines with a direct P–P
bond between four-coordinated phosphorus atoms as well as compounds with a P–P bond …

Racemic carborane-based bisphosphanes were obtained by dismutation reactions between
a carborane-based diphosphetane and diaryl dichalogenides. NMR spectroscopic and …

Abstract Bildung und Nachweis von Phosphinidenen (R P̈:) beim Zerfall von
Cyclophosphanen sowie bei der Reaktion von Dichlorphosphanen mit Metallen werden …

The insertion reaction of phosphinidene 'PH into H20, HgS, HF, and HC1 has been studied
by ah initio molecular orbital theory including electron correlation and zero-point energy …

Ph2PH or Ph (Me) PH yields (CF3) 2PPPh2 and (CF3) 2PP (Me) Ph, respectively, in addition
to (CF3) 2PH. In a similar reaction with H (Ph) P (CH2) 3P (Ph) H, the interesting …

The reaction of (Me3SI) 3SILI with f-BuPCI2 re-sults initially in (Me3Si) 3SIP (CI)(f-Bu) which
undergoes thermal rearrangement to (Me3SI) 2 (CI) SIP (f-BuXSIMe3) via a novel silicon …

In theprevious paper2 we reported the general reaction of a dipnicogen, 1 such as
Me2PPMe2 or Me2AsAsMe2, with an equimolar quantity of perfluoroalkylphosphinidine …