The search for extremely sterically demanding monodentate amide ligands to access main
group complexes in low-coordination numbers and highly reactive bonding modes is an …

A series of new germylene compounds has been synthesized offering systematic variation in
the σ‐and π‐capabilities of the α‐substituent and differing levels of reactivity towards E− H …

A family of chelating aryl-functionalized germylene ligands has been developed and
employed in the synthesis of their corresponding 16-electron Ni0 complexes …

Two extremely bulky amidinate ligands,[RC {N (Dip)}{N (Ar†)}]−(Dip= 2, 6-diisopropylphenyl;
Ar†= C6H2 {C (H) Ph2} 2Pri-2, 6, 4; R= 1-adamantyl (LAd), tert-butyl (LtBu)) have been …

BN and BB triple bonds induce C–H activation of acetone to yield a (2-propenyloxy)
aminoborane and an unsymmetrical 1-(2-propenyloxy)-2-hydrodiborene, respectively. DFT …

This work describes the synthesis and full characterization of elusive chloropnictenium ion
salts of the type [RAr* N (SiMe) ECl][A](RAr*= 2, 6‐(CHPh2)‐4‐R‐C6H2, R= Me, tBu; E= Sb …

The role of intramolecular metal⋅⋅⋅ π‐arene interactions has been investigated in the solid‐
state structures of a series of main group compounds supported by the bulky amide …

The reaction of the lithium salt of 1igand [1;(2, 6-i Pr2C6H3NH)(PPh2)] with GeCl2· dioxane
in 1: 1 stoichiometry gives a dimeric chlorogermylene,(2, 6-i Pr2C6H3NGeClPPh2) 2 (2) …

The chemistry of extremely bulky amide ligands is troubled by difficulties in deprotonation of
the parent amine. As an alternative route to superbulky amide reagents, the addition of polar …

The diphosphinoamine ligands [(Ph2P) 2N (Ar); 1 (Ar= C6H5), 2 (Ar= 2, 6-iPr2C6H3)] were
effectively utilized in Buchwald–Hartwig coupling of a range of sterically demanding …