Emergence of palladium (IV) chemistry in synthesis and catalysis
P Sehnal, RJK Taylor, IJS Fairlamb - Chemical reviews, 2010 - ACS Publications
Palladium-catalyzed bond-forming processes (eg, CC, CX, CY; X) F; Y) NR2, OR, SR, etc.)
represent essential tools for the synthetic chemist. A fascinating myriad of adventurous and …
represent essential tools for the synthetic chemist. A fascinating myriad of adventurous and …
Carbon–Heteroatom Bond-Forming Reductive Elimination from Palladium (IV) Complexes
JM Racowski, MS Sanford - Higher Oxidation State Organopalladium and …, 2011 - Springer
This work provides a comprehensive review (1986–2010) of the synthesis, characterization,
and reactivity of palladium (IV) complexes that undergo carbon–heteroatom bond-forming …
and reactivity of palladium (IV) complexes that undergo carbon–heteroatom bond-forming …
Palladium-Catalyzed peri-Selective Chalcogenation of Naphthylamines with Diaryl Disulfides and Diselenides via C–H Bond Cleavage
M Iwasaki, W Kaneshika, Y Tsuchiya… - The Journal of …, 2014 - ACS Publications
A palladium-catalyzed and picolinamide-directed C–H thiolation of naphthylamine
derivatives with diaryl disulfides has been developed to provide a convenient route to 8 …
derivatives with diaryl disulfides has been developed to provide a convenient route to 8 …
Mechanistic and Computational Studies of Oxidatively-Induced Aryl−CF3 Bond-Formation at Pd: Rational Design of Room Temperature Aryl Trifluoromethylation
This article describes the rational design of first generation systems for oxidatively induced
Aryl− CF3 bond-forming reductive elimination from PdII. Treatment of (dtbpy) PdII …
Aryl− CF3 bond-forming reductive elimination from PdII. Treatment of (dtbpy) PdII …
Palladium (II), platinum (II), ruthenium (II) and mercury (II) complexes of potentially tridentate Schiff base ligands of (E, N, O) type (E= S, Se, Te): Synthesis, crystal …
Schiff bases of 2-hydroxybenzophenone (HBP)(C6H5)(2-HOC6H4) CN (CH2) nEAr (L1/L2:
E= S, Ar= Ph, n= 2/3; L3/L4: E= Se, Ar= Ph, n= 2/3; L5/L6: E= Te, Ar= 4-MeOC6H4, n= 2/3) …
E= S, Ar= Ph, n= 2/3; L3/L4: E= Se, Ar= Ph, n= 2/3; L5/L6: E= Te, Ar= 4-MeOC6H4, n= 2/3) …
Organopalladium and platinum chemistry in oxidising milieu as models for organic synthesis involving the higher oxidation states of palladium
AJ Canty - Dalton Transactions, 2009 - pubs.rsc.org
This perspective focuses on the higher oxidation state (III, IV) organometallic chemistry of
palladium involving a range of strong oxidants, with consideration of platinum chemistry …
palladium involving a range of strong oxidants, with consideration of platinum chemistry …
Palladium-catalysed direct thiolation and selenation of aryl C–H bonds assisted by directing groups
M Iwasaki, Y Nishihara - Dalton Transactions, 2016 - pubs.rsc.org
Direct chalcogenation of aryl C–H bonds has attracted a lot of attention because
arylcharcogen compounds represent useful building blocks in bioactive molecules and …
arylcharcogen compounds represent useful building blocks in bioactive molecules and …
Schiff bases of 1′-hydroxy-2′-acetonaphthone containing chalcogen functionalities and their complexes with and (p-cymene) Ru (II), Pd (II), Pt (II) and Hg (II) …
Schiff bases of 1′-hydroxy-2′-acetonaphthone (HAN) containing chalcogen
functionalities, 1-HO–C10H6-2-CH3) CN–(CH2) nEC6H4-4-R (R= H or OMe; n= 2 or 3; E= S …
functionalities, 1-HO–C10H6-2-CH3) CN–(CH2) nEC6H4-4-R (R= H or OMe; n= 2 or 3; E= S …
Palladium-Catalyzed Direct Selanylation of Chalcogenophenes and Arenes Assisted by 2-(Methylthio) amide
The direct and selective conversion of a C–H bond into a C–Se bond remains a significant
challenge, which is even more intricate with substrates having an innate regioselectivity …
challenge, which is even more intricate with substrates having an innate regioselectivity …
Platinum Model Studies for Palladium-Catalyzed Oxidative Functionalization of C− H Bonds
AR Dick, JW Kampf, MS Sanford - Organometallics, 2005 - ACS Publications
The synthesis of (CN) PtII (acac) complexes (CN= benzo [h] quinoline, 8-methylquinoline)
and their oxidation with PhI (OAc) 2 are reported as a model system for palladium-catalyzed …
and their oxidation with PhI (OAc) 2 are reported as a model system for palladium-catalyzed …