Transition-metal-catalyzed C–H activation has developed a contemporary approach to the
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …

The functionalization of C–H bonds and the visible light photoredox catalysis represent two
prominent challenges in organic chemistry. In this regard, the combination of visible-light …

The selective functionalization of remote C–H bonds via intramolecular hydrogen atom
transfer (HAT) is transformative for organic synthesis. This radical-mediated strategy …

The development and application of efficient, convenient, selective, and environmentally
benign synthetic methods is highly desirable in organic chemistry. With this requirement …

Mn (III)-mediated formal [3+ 3]-annulation has been developed using readily available vinyl
azides and cyclopropanols with a wide range of substituents. Vinyl azides were successfully …

This review highlights synthetically useful transformations of organic free-radicals in which a
key step is relocation of the radical site by intramolecular abstraction either of a hydrogen …

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Service Library Service Help Contact Portal SynOpen Full-text search Full-text search Author …

Cascade, domino, or tandem processes, that link together two or more transformations in
one pot, are increasing in popularity because they lead to improvements in synthetic …

C− C bond formation reactions that take place through organoiron species sometimes
exhibit radical-like character. The reaction of N-(2-iodophenylmethyl) dialkylamine with a …

Copper-catalyzed benzylic C− H oxygenation under an oxygen atmosphere was developed
starting from carbonitriles and Grignard reagents via NH imine intermediates. The present …