Ruthenium (II)-catalyzed C–H bond activation and functionalization

PB Arockiam, C Bruneau, PH Dixneuf - Chemical reviews, 2012 - ACS Publications
The catalytic functionalization of unreactive C− H bonds has recently brought a revolution in
synthetic methodologies for the production of pharmaceuticals and natural products and for …

Direct observation of the oxidative addition of the aryl carbon− oxygen bond to a ruthenium complex and consideration of the relative reactivity between aryl carbon …

S Ueno, E Mizushima, N Chatani… - Journal of the American …, 2006 - ACS Publications
When RuH2 (CO)(PPh3) 3 was reacted with 2, 2-dimethyl-1-(2-p-tolylphenyl) propan-1-one
(2), the ruthenium− aryloxy complex 3 was obtained in 76% yield. The structure of this …

A convenient system for improving the efficiency of first-generation ruthenium olefin metathesis catalysts

GS Forman, AE McConnell, RP Tooze… - …, 2005 - ACS Publications
The performance of certain olefin metathesis reactions catalyzed by Grubbs catalysts has
been enhanced by the simple addition of phenol. Addition of phenol to self-metathesis …

Nickel-catalyzed one-pot deoxygenation and reductive homocoupling of phenols via C–O Activation using TCT reagent

N Iranpoor, F Panahi - Organic letters, 2015 - ACS Publications
A new method for C–O bond activation of phenolic compounds has been achieved using 2,
4, 6-trichloro-1, 3, 5-triazine to utilize in one-pot Ni-catalyzed deoxygenation and reductive …

Advances in ruthenium catalysis. Novel catalytic reactions via η3-allylruthenium intermediates

T Kondo, TA Mitsudo - Current Organic Chemistry, 2002 - ingentaconnect.com
Recent developments in ruthenium-catalyzed chemo-, regio-, and stereoselective CC bond
forming reactions as well as a CC bond cleaving reaction via an η3-allylruthenium …

Iridium-Catalyzed Reaction of 1-Naphthols, N-(1-Naphthyl)benzenesulfonamides, and Salicylaldehyde with Internal Alkynes

Y Nishinaka, T Satoh, M Miura… - Bulletin of the …, 2001 - academic.oup.com
Naphthols efficiently couple with internal alkynes via cleavage of the C–H bond at the peri-
position in the presence of a catalyst system of [IrCl (cod)] 2/PBu t 3 to selectively afford the …

Double bond migration in S allyl systems catalysed by [RuClH (CO)(PPh3) 3]

N Kuźnik, S Krompiec, T Bieg, S Baj, K Skutil… - Journal of …, 2003 - Elsevier
Reactions of S allyl systems (allyl sulphides of R S allyl type, where R= Et, allyl, Ph,
Me3C, Ph3C, as well as of allyl phenyl sulphoxide, allyl phenyl sulphone, 2, 5-dihydro-1, 1 …

Ruthenium‐Catalyzed Synthesis of Alkylidenecyclobutenes via Head‐to‐Head Dimerization of Propargylic Alcohols and Cyclobutadiene–Ruthenium Intermediates

J Le Paih, S Dérien, B Demerseman… - … A European Journal, 2005 - Wiley Online Library
The reaction of propargylic alcohols with carboxylic acid, or phenol derivatives, in the
presence of the precatalyst [RuCl (cod)(C5Me5)] leads selectively to a variety of …

Lactonbildung durch Rh‐katalysierte Öffnung von Cyclobutanonen

M Murakami, T Tsuruta, Y Ito - Angewandte Chemie, 2000 - Wiley Online Library
Als koordinierende Gruppe unterstützt der Phenolrest in entsprechend substituierten
Cyclobutanonen die RhI‐katalysierte Aktivierung der C‐C‐Bindung zwischen dem Carbonyl …

C–O and C–S bond activation of allyl esters, ethers, and sulfides by low valent ruthenium complexes

JG Planas, T Marumo, Y Ichikawa, M Hirano… - Journal of Molecular …, 1999 - Elsevier
Allyl carboxylates or ethers react with Ru (cod)(cot)(1)[cod: 1, 5-cyclooctadiene, cot: 1, 3, 5-
cyclooctatriene] in the presence of monodentate tertiary phosphines such as PMe3, PEt3 …