Probing the formation and degradation of chemical interactions from model molecule/metal oxide to buried polymer/metal oxide interfaces

S Pletincx, LLI Fockaert, JMC Mol, T Hauffman… - npj Materials …, 2019 - nature.com
The mechanisms governing coating/metal oxide delamination are not fully understood,
although adhesive interactions at the interface are considered to be an important …

Nanosensors for monitoring early stages of metallic corrosion

L Exbrayat, S Salaluk, M Uebel, R Jenjob… - ACS Applied Nano …, 2019 - ACS Publications
A new generation of nanosensors based on mesoporous silica nanocapsules with the ability
to monitor the onset of metallic corrosion is successfully developed and tested on 304 …

Limiting current density of oxygen reduction under ultrathin electrolyte layers: from the micrometer range to monolayers

X Zhong, M Schulz, CH Wu, M Rabe, A Erbe… - …, 2021 - Wiley Online Library
The oxygen reduction reaction (ORR) under ultrathin electrolyte layers is a key reaction in
many processes, from atmospheric corrosion to energy conversion in fuel cells. However …

An in situ spectro-electrochemical monitoring of aqueous effects on polymer/metal oxide interfaces

S Pletincx, JMC Mol, H Terryn, A Hubin… - Journal of …, 2019 - Elsevier
A spectro-electrochemical setup of Fourier transform infrared spectroscopy (FTIR) in the
Kretschmann geometry and odd random phase multisine electrochemical impedance …

[HTML][HTML] On the rate determining step of cathodic delamination of delamination-resistant organic coatings

N Khayatan, JM Prabhakar, E Jalilian, N Madelat… - Corrosion …, 2024 - Elsevier
Cation transport from defect site to delamination front and oxygen reduction at the
polymer/metal interface are the two processes that are proposed to control the kinetics of …

Cyclodextrins as carriers for organic corrosion inhibitors in organic coatings

A Altin, M Rohwerder, A Erbe - Journal of The Electrochemical …, 2017 - iopscience.iop.org
Coatings are widely applied on metal surfaces for protection against corrosion. Once a
coating is damaged and a defect is filled by aqueous solutions, delamination of the coating …

The protection zone: A long-range corrosion protection mechanism around conducting polymer particles in composite coatings: Part I. polyaniline and polypyrrole

A Merz, M Uebel, M Rohwerder - Journal of the Electrochemical …, 2019 - iopscience.iop.org
Abstract In recent years Intrinsically Conducting Polymers (ICPs), such as polyaniline and
polypyrrole, have become key materials in the search for high-performance coatings for the …

Fabrication of robust reference tips and reference electrodes for Kelvin probe applications in changing atmospheres

M Uebel, A Vimalanandan, A Laaboudi, S Evers… - Langmuir, 2017 - ACS Publications
The scanning Kelvin probe (SKP) is a versatile method for the measurement of the Volta
potential difference between a sample and the SKP-tip (ΔψsampleSKP-tip). Based on …

Analysis of polymer/oxide interfaces under ambient conditions–An experimental perspective

A González-Orive, I Giner, T De Los Arcos… - Applied Surface …, 2018 - Elsevier
In many different hybrid materials and materials composites polymers adhere to bulk oxides
or oxide covered metal. The formed polymer/oxide interfaces are of crucial importance for …

A modelling approach on the impact of an oxide layer on the hydrogen permeation through iron membranes in the Devanathan-Stachurski cell

L Vecchi, D Pecko, N Van den Steen, MH Mamme… - Electrochimica …, 2018 - Elsevier
The diffusion and trapping of hydrogen in iron alloys is commonly studied using the
Devanathan-Stachurski cell. In this cell, the hydrogen flux through a metal membrane is …