The hallmark of nucleophilic phosphine catalysis is the initial nucleophilic addition of a
phosphine to an electrophilic starting material, producing a reactive zwitterionic …

Asymmetric phosphine catalysis showcasing remarkable progress over the past two
decades has emerged as a key synthetic platform for the creation of molecular frameworks …

1. INTRODUCTION The carbon− carbon bond forming reactions is one of the most important
reactions in organic chemistry, and therefore has been and remains an important and a …

Nucleophilic phosphine catalysis is a practical and powerful tool for the synthesis of various
heterocyclic compounds with the advantages of environmentally friendly, metal-free, and …

Since about the year 2000, the research area of asymmetric organocatalysis has grown
rapidly to become one of the most fascinating and current fields in organic chemistry. In the …

This review discusses the tertiary phosphines possessing various chiral skeletons that have
been used in asymmetric nucleophilic organocatalytic reactions, including annulations of …

The prevalence of nitrogen containing heterocycles in natural products and pharmaceuticals
is a doubtless fact. In this review, recent applications of a stereoselective aza-Michael …

The organocatalytic intramolecular aza-Michael reaction gives access to enantiomerically
enriched nitrogen-containing heterocycles in a very simple manner. Enals, enones …

The first phosphine-catalyzed highly enantioselective [3+ 3] cycloaddition of Morita–Baylis–
Hillman carbonates with C, N-cyclic azomethine imines is described. Using a spirocyclic …

Beyond a doubt organocatalysis belongs to the most exciting and innovative chapters of
organic chemistry today. Organocatalysis has emerged not only as a complement to metal …