Kesterite solar cells: insights into current strategies and challenges

M He, C Yan, J Li, MP Suryawanshi, J Kim… - Advanced …, 2021 - Wiley Online Library
Earth‐abundant and environmentally benign kesterite Cu2ZnSn (S, Se) 4 (CZTSSe) is a
promising alternative to its cousin chalcopyrite Cu (In, Ga)(S, Se) 2 (CIGS) for photovoltaic …

Point defect engineering in thin-film solar cells

JS Park, S Kim, Z Xie, A Walsh - Nature Reviews Materials, 2018 - nature.com
Control of defect processes in photovoltaic materials is essential for realizing high-efficiency
solar cells and related optoelectronic devices. Native defects and extrinsic dopants tune the …

Device Postannealing Enabling over 12% Efficient Solution‐Processed Cu2ZnSnS4 Solar Cells with Cd2+ Substitution

Z Su, G Liang, P Fan, J Luo, Z Zheng, Z Xie… - Advanced …, 2020 - Wiley Online Library
Abstract Kesterite Cu2ZnSnS4 is a promising photovoltaic material containing low‐cost,
earth‐abundant, and stable semiconductor elements. However, the highest power …

Identifying the origin of the V oc deficit of kesterite solar cells from the two grain growth mechanisms induced by Sn 2+ and Sn 4+ precursors in DMSO solution

Y Gong, Y Zhang, Q Zhu, Y Zhou, R Qiu… - Energy & …, 2021 - pubs.rsc.org
Kesterite Cu2ZnSn (S, Se) 4 solar cells fabricated from DMSO molecular solutions exhibit
very different open circuit voltage (Voc) when the tin precursor has a different oxidation state …

Ag incorporation with controlled grain growth enables 12.5% efficient kesterite solar cell with open circuit voltage reached 64.2% Shockley–Queisser limit

Y Gong, R Qiu, C Niu, J Fu, E Jedlicka… - Advanced Functional …, 2021 - Wiley Online Library
The large open‐circuit voltage deficit (Voc, def) is the key issue that limits kesterite
(Cu2ZnSn (S, Se) 4,[CZTSSe]) solar cell performance. Substitution of Cu+ by larger ionic …

Defect engineering in multinary earth‐abundant chalcogenide photovoltaic materials

D Shin, B Saparov, DB Mitzi - Advanced Energy Materials, 2017 - Wiley Online Library
Application of zinc‐blende‐related chalcogenide absorbers such as CdTe and Cu (In, Ga)
Se2 (CIGSe) has enabled remarkable advancement in laboratory‐and commercial‐scale …

Efficient and Composition‐Tolerant Kesterite Cu2ZnSn(S, Se)4 Solar Cells Derived From an In Situ Formed Multifunctional Carbon Framework

X Xu, L Guo, J Zhou, B Duan, D Li, J Shi… - Advanced Energy …, 2021 - Wiley Online Library
Broadening the processing window is of high importance for developing efficient Cu2ZnSn
(S, Se) 4 (CZTSSe) solar cells. Herein, a high efficiency (active‐area: 13.5%) of CZTSSe …

The current status and future prospects of kesterite solar cells: a brief review

X Liu, Y Feng, H Cui, F Liu, X Hao… - Progress in …, 2016 - Wiley Online Library
Kesterite‐based solar cells are attracting considerable attention in recent years, owing to the
reduced toxicity and greater abundance of their constituent elements. In this brief review, we …

Is the Cu/Zn disorder the main culprit for the voltage deficit in kesterite solar cells?

S Bourdais, C Choné, B Delatouche… - Advanced Energy …, 2016 - Wiley Online Library
Photovoltaic thin film solar cells based on kesterite Cu2ZnSn (Sx, Se1–x) 4 compounds
(CZTSSe) have reached> 12% sunlight‐to‐electricity conversion efficiency. This is still far …

Point defects, compositional fluctuations, and secondary phases in non-stoichiometric kesterites

S Schorr, G Gurieva, M Guc… - Journal of Physics …, 2019 - iopscience.iop.org
The efficiency of kesterite-based solar cells is limited by various non-ideal recombination
paths, amongst others by a high density of defect states and by the presence of binary or …