Metal–organic frameworks (MOFs) based on group 3 and 4 metals are considered as the
most promising MOFs for varying practical applications including water adsorption, carbon …

A family of thorium complexes featuring the redox-noninnocent pyridinediimine ligand
MesPDIMe was synthesized, including (MesPDIMe) ThCl4 (1-Th),(MesPDIMe) ThCl3 …

A new hexanuclear plutonium cluster has been stabilized in aqueous media with acetate
ligands. To probe the formation of such a complex structure, visible–near infrared (vis–NIR) …

Abstract Uranium (IV) complexation by 2‐furoic acid (2‐FA) was examined to better
understand the effects of ligand identity and reaction conditions on species formation and …

The fundamental hydrolysis behavior of tetravalent actinide cations (An4+) with a high
charge is crucial for understanding their solution chemistry, particularly in nuclear fuel …

Herein, we report the synthesis and structures of two novel mixed-metal clusters denoted as
Th9Ag6 and Th9Ag12. Both clusters feature unprecedented Th9 cores. The cores are …

Isolating isomorphic compounds of tetravalent actinides (ie, ThIV, UIV, NpIV, and PuIV)
improve our understanding of the bonding behavior across the series, in addition to their …

Thorium (IV) complexes are currently attracting intense attention from inorganic chemists
due to the development of liquid-fluoride thorium reactors and the fact that thorium (IV) is …

The synthesis and structural chemistry of two tetravalent thorium compounds precipitated
from acidic bromide solutions are described. One of the phases,[Th (H2O) 10] Br4 (1), has …

Five novel tetravalent thorium (Th) compounds that consist of Th (H2O) x Cl y structural units
were isolated from acidic aqueous solutions using a series of nitrogen-containing …