Empirical Hydrogen Bonding Donor (HBD) Parameters of Organic Solvents Using Solvatochromic Probes–A Critical Evaluation

S Spange, N Weiß - ChemPhysChem, 2023 - Wiley Online Library
The solvatochromicity of established solvatochromic UV/Vis probes, which appear to be
sensitive to the so‐called hydrogen bond donor (HBD) property of the solvent, is analysed …

Recent progress in homogeneous hydrogenation of carbon dioxide to methanol

SJ Poormohammadian, F Bahadoran… - Reviews in Chemical …, 2023 - degruyter.com
The requirement of running a new generation of fuel production is inevitable due to the
limitation of oil production from reservoirs. On the other hand, enhancing the CO2 …

Effect of solvent polarity and electrophilicity on quantum yields and solvatochromic shifts of single-walled carbon nanotube photoluminescence

BA Larsen, P Deria, JM Holt, IN Stanton… - Journal of the …, 2012 - ACS Publications
In this work, we investigate the impact of the solvation environment on single-walled carbon
nanotube (SWCNT) photoluminescence quantum yield and optical transition energies (Eii) …

Complementary interpretation of ET (30) polarity parameters of ionic liquids

S Spange, C Lienert, N Friebe… - Physical Chemistry …, 2020 - pubs.rsc.org
Reichardt's empirical ET (30) polarity parameter has been established as appropriate
polarity scale for ionic liquids. In this study, the relationships of ET (30) of ionic liquids with …

Fine tuning of a solvatochromic fluorophore for selective determination of Fe3+: a new type of benzimidazole-based anthracene-coupled receptor

DY Lee, N Singh, DO Jang - Tetrahedron letters, 2011 - Elsevier
We synthesized a novel benzimidazole-based, anthracene-coupled fluorescent receptor
capable of recognizing and estimating the concentrations of Fe3+ in semi-aqueous solution …

Structural and functional model systems for analysis of the active center of nitrile hydratase

T Yano, T Ozawa, H Masuda - Chemistry letters, 2008 - academic.oup.com
The unique active site structure of nitrile hydratase (NHase) has a central metal ion (CoIII or
FeIII) coordinated by two amide nitrogens from the peptide backbone, one cysteine sulfur …

Anion-Induced Structural Diversity and Optical Chromism in a Series of Cyano-Bridged Heterometallic 3d-4f Coordination Polymers

F Artizzu, L Pilia, A Serpe, D Mara, MF Casula… - Molecules, 2023 - mdpi.com
The self-assembly reaction of the neutral dicyano-bis (1, 10-phenanthroline) iron (II)
complex with lanthanide ions (Ln= Eu (III), Gd (III), Er (III)) provided two different classes of …

Solvatochromic and Ionochromic Effects of Iron (II) bis (1, 10-phenanthroline) dicyano: a Theoretical Study

I Georgieva, AJA Aquino, N Trendafilova… - Inorganic …, 2010 - ACS Publications
Solvatochromic and ionochromic effects of the iron (II) bis (1, 10-phenanthroline) dicyano
(Fe (phen) 2 (CN) 2) complex were investigated by means of combined DFT/TDDFT …

Modeling the Effect of Lithium Superoxide Solvation and Surface Reduction Kinetics on Discharge Capacity in Lithium–Oxygen Batteries

TP Batcho, G Leverick, Y Shao-Horn… - The Journal of …, 2019 - ACS Publications
Li–O2 batteries could potentially yield significantly higher capacities than Li-ion batteries.
Achieving high capacity requires efficient void-filling of the cathode by the insoluble …

Co(III) Complexes with N2(SO)2-Type Equatorial Planar Ligands Similar to the Active Center of Nitrile Hydratase:  Role of the Sulfenate Group in the Enzymatic …

T Yano, Y Wasada-Tsutsui, H Arii… - Inorganic …, 2007 - ACS Publications
In order to gain an understanding of the role of the sulfenyl group of nitrile hydratase
(NHase), a new Co (III) complex with a sulfenyl-type ligand (LC O: N2 (SO) 2), Na [CoIII (LC …