Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Covalent organic frameworks: design, synthesis, and functions

K Geng, T He, R Liu, S Dalapati, KT Tan, Z Li… - Chemical …, 2020 - ACS Publications
Covalent organic frameworks (COFs) are a class of crystalline porous organic polymers with
permanent porosity and highly ordered structures. Unlike other polymers, a significant …

Metal–organic frameworks with Lewis acidity: synthesis, characterization, and catalytic applications

Z Hu, D Zhao - CrystEngComm, 2017 - pubs.rsc.org
Metal–organic frameworks (MOFs) are exquisitely architected through the pervasive
coordination bonds between inorganic metal nodes and organic ligands. Marked by high …

Mixed-metal or mixed-linker metal organic frameworks as heterogeneous catalysts

A Dhakshinamoorthy, AM Asiri, H Garcia - Catalysis Science & …, 2016 - pubs.rsc.org
Metal organic frameworks (MOFs) are among the most studied heterogeneous catalysts that
have been applied to promote a wide range of reactions. Most of the initial studies on the …

Facile synthesis of MIL-100 (Fe) under HF-free conditions and its application in the acetalization of aldehydes with diols

F Zhang, J Shi, Y Jin, Y Fu, Y Zhong, W Zhu - Chemical engineering journal, 2015 - Elsevier
Mesoporous iron (III) carboxylate [MIL-100 (Fe)] has been successfully synthesized by a
simple unappreciated low-temperature (< 100° C) route via the reaction of ferric nitrate and …

Metal organic frameworks as heterogeneous catalysts for the production of fine chemicals

A Dhakshinamoorthy, M Opanasenko… - Catalysis Science & …, 2013 - pubs.rsc.org
This review focuses on the use of metal organic frameworks (MOFs) as catalysts for the
synthesis of fine chemicals. While petrochemistry is characterized by gas phase reactions, in …

Exploring the catalytic performance of a series of bimetallic MIL-100 (Fe, Ni) MOFs

M Giménez-Marqués, A Santiago-Portillo… - Journal of Materials …, 2019 - pubs.rsc.org
A series of mixed-metal FeIII/NiII metal–organic frameworks (MOFs) of the MIL-100 type
containing different metal ratios have been synthesized de novo, following an approach that …

Polyoxometalates confined in the mesoporous cages of metal–organic framework MIL-100 (Fe): efficient heterogeneous catalysts for esterification and acetalization …

F Zhang, Y Jin, J Shi, Y Zhong, W Zhu… - Chemical Engineering …, 2015 - Elsevier
Tungstophosphoric heteropolyacid (HPW) has been encapsulated in a mesoporous metal–
organic framework (MOF), MIL-100 (Fe), by a simple low-temperature (< 100° C) HF-free …

Direct synthesis, structural features, and enhanced catalytic activity of the basolite F300-like semiamorphous Fe-BTC framework

M Sanchez-Sanchez, I de Asua, D Ruano… - Crystal Growth & …, 2015 - ACS Publications
Paradoxically, one of the most widely and successfully tested metal–organic framework
(MOF)-based catalysts, ie, the Fe-BTC material commercialized as Basolite F300, entails a …

Copper-based MOF-74 material as effective acid catalyst in Friedel–Crafts acylation of anisole

G Calleja, R Sanz, G Orcajo, D Briones, P Leo… - Catalysis Today, 2014 - Elsevier
Metal organic frameworks (MOFs) are emerging potential materials for catalytic applications.
Among them, the honeycomb M 2 (dhtp) family, also known as MOF-74 or CPO-27 materials …