Cofactor-mimetic aerobic oxidation has conceptually merged with catalysis of syngas
reactions to form a wide range of Markovnikov-selective olefin radical …

This review covers the structures and biological activities of peroxy natural products from a
wide variety of terrestrial fungi, higher plants, and marine organisms. Syntheses that confirm …

A Co-catalyzed selective C–C bond cleavage followed by the silylperoxylation of alkene
substrates generated a series of alkylsilyl peroxides with good yields and selectivities …

Covering: up to early 2016 Marine sponges are widely known as a rich source of natural
products, especially of polyketide origin, with a wealth of chemical diversity. Within this vast …

The cobalt-catalyzed peroxidation of silyl enol ethers with molecular oxygen and
triethylsilane provided silyl monoperoxyketals in 54%–96% yield. These compounds serve …

A facile synthesis of carbo-and heterocycles via Fe (III)-catalyzed alkene
hydrofunctionalization has been developed. Various alkenes bearing a leaving group could …

Written by a" who is who" of leading organic chemists, this anniversary volume represent the
Organic Reactions editors' choice of the most important, ground-breaking and versatile …

Mycaperoxides are natural endoperoxides isolated from different Mycale genus sponges,
showing significant antiviral or antibacterial activities. We report herein the first total …

En route to the synthesis of plakortolide E and I, we prepared a β-hydroperoxy vinyl epoxide,
obtained from (R)-epichlorhydrin in 13 steps and 30% yield, via chemoselective …

Endoperoxide motifs can be found in a plethora of natural products and have demonstrated
toxicity to a number of cancer cell lines. The synthesis of these endoperoxides usually …