The biologically relevant coordination chemistry of iron and nitric oxide: electronic structure and reactivity
Nitric oxide (NO) is an important signaling molecule that is involved in a wide range of
physiological and pathological events in biology. Metal coordination chemistry, especially …
physiological and pathological events in biology. Metal coordination chemistry, especially …
Reactive high-valent iron intermediates in enhancing treatment of water by ferrate
Efforts are being made to tune the reactivity of the tetraoxy anion of iron in the+ 6 oxidation
state (FeVIO42–), commonly called ferrate, to further enhance its applications in various …
state (FeVIO42–), commonly called ferrate, to further enhance its applications in various …
CoN1O2 Single‐Atom Catalyst for Efficient Peroxymonosulfate Activation and Selective Cobalt(IV)=O Generation
High‐valent metal‐oxo (HVMO) species are powerful non‐radical reactive species that
enhance advanced oxidation processes (AOPs) due to their long half‐lives and high …
enhance advanced oxidation processes (AOPs) due to their long half‐lives and high …
Ultrahigh peroxymonosulfate utilization efficiency over CuO nanosheets via heterogeneous Cu (III) formation and preferential electron transfer during degradation of …
In persulfate activation by copper-based catalysts, high-valent copper (Cu (III)) is an
overlooked reactive intermediate that contributes to efficient persulfate utilization and …
overlooked reactive intermediate that contributes to efficient persulfate utilization and …
Unraveling the overlooked involvement of high-valent cobalt-oxo species generated from the cobalt (II)-activated peroxymonosulfate process
Sulfate radical (SO4•–) is widely recognized as the predominant species generated from the
cobalt (II)-activated peroxymonosulfate (PMS) process. However, in this study, it was …
cobalt (II)-activated peroxymonosulfate (PMS) process. However, in this study, it was …
Single-Atom MnN5 Catalytic Sites Enable Efficient Peroxymonosulfate Activation by Forming Highly Reactive Mn(IV)–Oxo Species
Four-nitrogen-coordinated transitional metal (MN4) configurations in single-atom catalysts
(SACs) are broadly recognized as the most efficient active sites in peroxymonosulfate (PMS) …
(SACs) are broadly recognized as the most efficient active sites in peroxymonosulfate (PMS) …
Cu-doped CoOOH activates peroxymonosulfate to generate high-valent cobalt-oxo species to degrade organic pollutants in saline environments
A Cu doped CoOOH-activated peroxymonosulfate (CoCu10/PMS) process was developed
to enable the generation of Co (IV)= O for efficient oxidation of pollutants in saline water. The …
to enable the generation of Co (IV)= O for efficient oxidation of pollutants in saline water. The …
Metal‐corrole‐based porous organic polymers for electrocatalytic oxygen reduction and evolution reactions
Integrating molecular catalysts into designed frameworks often enables improved catalysis.
Compared with porphyrin‐based frameworks, metal‐corrole‐based frameworks have been …
Compared with porphyrin‐based frameworks, metal‐corrole‐based frameworks have been …
Transition metal single-atom embedded on N-doped carbon as a catalyst for peroxymonosulfate activation: A DFT study
Single-atom catalysts perform excellently in peroxymonosulfate (PMS)-based advanced
oxidation processes (AOPs), for which the generation of reactive oxygen species (ROS) is …
oxidation processes (AOPs), for which the generation of reactive oxygen species (ROS) is …
Revealing the Generation of High-Valent Cobalt Species and Chlorine Dioxide in the Co3O4-Activated Chlorite Process: Insight into the Proton Enhancement Effect
R Su, N Li, Z Liu, X Song, W Liu, B Gao… - Environmental …, 2023 - ACS Publications
A Co3O4-activated chlorite (Co3O4/chlorite) process was developed to enable the
simultaneous generation of high-valent cobalt species [Co (IV)] and ClO2 for efficient …
simultaneous generation of high-valent cobalt species [Co (IV)] and ClO2 for efficient …