Alkylidenecarbenes, alkylidenecarbenoids, and competing species: Which is responsible for vinylic nucleophilic substitution,[1+ 2] cycloadditions, 1, 5-CH insertions …
R Knorr - Chemical reviews, 2004 - ACS Publications
The Fritsch-Buttenberg-Wiechell (FBW)“rearrangement” was discovered1 as the formation of
diarylacetylenes (6) from 2, 2-diaryl-1-halogenoalkenes (1) under the action of sodium …
diarylacetylenes (6) from 2, 2-diaryl-1-halogenoalkenes (1) under the action of sodium …
Synthesis and aromaticity of metallacyclopropene complexes
B Fu, W Bai, Y Li, W Jiang - Chemical Communications, 2024 - pubs.rsc.org
Metallacycloprop-1-ene and metallacycloprop-2-ene complexes are the smallest
unsaturated metallacycles, and have attracted continuing attention for their importance in …
unsaturated metallacycles, and have attracted continuing attention for their importance in …
A general bifunctional catalyst for the anti-Markovnikov hydration of terminal alkynes to aldehydes gives enzyme-like rate and selectivity enhancements
DB Grotjahn, DA Lev - Journal of the American Chemical Society, 2004 - ACS Publications
A new, bifunctional catalyst for anti-Markovnikov hydration of terminal alkynes to aldehydes
(6) allows practical room-temperature hydration of alkyl-substituted alkynes. Other …
(6) allows practical room-temperature hydration of alkyl-substituted alkynes. Other …
Ruthenium-Catalyzed Hydration of 1-Alkynes to Give Aldehydes: Insight into anti-Markovnikov Regiochemistry
M Tokunaga, T Suzuki, N Koga… - Journal of the …, 2001 - ACS Publications
The mechanism of the selective conversion of 1-alkynes to aldehydes by hydration was
investigated by isolating organic and organometallic byproducts, deuterium-labeling …
investigated by isolating organic and organometallic byproducts, deuterium-labeling …
Ruthenium and osmium vinylidene complexes and some related compounds
A review of the large number of studies completed during the current decade on the
chemistry of ruthenium and osmium vinylidene complexes is presented. Interest in these …
chemistry of ruthenium and osmium vinylidene complexes is presented. Interest in these …
Convenient Synthesis of [(η5-C5Me5)Ru(NCMe)3]PF6 and the Phosphine Derivatives [(η5-C5Me5)Ru(PR3)2(NCMe)]PF6
B Steinmetz, WA Schenk - Organometallics, 1999 - ACS Publications
A convenient, high-yield (91%) synthesis of [(η5-C5Me5) Ru (NCMe) 3] PF6 (4− PF6) by zinc
reduction of [(η5-C5Me5) RuCl2] n (1) in acetonitrile solution is described. Two acetonitrile …
reduction of [(η5-C5Me5) RuCl2] n (1) in acetonitrile solution is described. Two acetonitrile …
New ruthenium vinylidene complexes as intermediates for the access to. sigma.-acetylide and unsymmetrical trans-diynyl, alkynyl metal complexes. Crystal structures …
D Touchard, P Haquette, N Pirio, L Toupet… - …, 1993 - ACS Publications
Metal-acetylide complexes attract interest as precur-sors of molecules containing a linear
array and delocalizable systems, 1'2 or polymeric materials, 2 in the search of interaction …
array and delocalizable systems, 1'2 or polymeric materials, 2 in the search of interaction …
Mononuclear Fe (I) and Fe (II) acetylene adducts and their reductive protonation to terminal Fe (IV) and Fe (V) carbynes
The activity of nitrogenase enzymes, which catalyze the conversion of atmospheric
dinitrogen to bioavailable ammonia, is most commonly assayed by the reduction of …
dinitrogen to bioavailable ammonia, is most commonly assayed by the reduction of …
Metallacumulenes: from vinylidenes to metal polycarbides
JP Selegue - Coordination chemistry reviews, 2004 - Elsevier
Metallacumulenes and carbide complexes exhibit diverse structures and modes of reactivity.
This review presents an overview of work in the author's research group on vinylidene …
This review presents an overview of work in the author's research group on vinylidene …
Alternative Mechanisms of the Alkyne to Vinylidene Isomerization Promoted by Half-Sandwich Ruthenium Complexes. X-ray Crystal Structures of [Cp*RuCCHCOOMe(dippe)][BPh4] and [Cp*RuH(C⋮ …
The complex [Cp* RuCl (dippe)] reacts with 1-alkynes in MeOH in the presence of NaBPh4,
yielding the metastable hydrido− alkynyl derivatives [Cp* Ru (H)(C⋮ CR)(dippe)][BPh4](R …
yielding the metastable hydrido− alkynyl derivatives [Cp* Ru (H)(C⋮ CR)(dippe)][BPh4](R …