Electrochemical late-stage functionalization

Y Wang, S Dana, H Long, Y Xu, Y Li… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) constitutes a powerful strategy for the assembly or
diversification of novel molecular entities with improved physicochemical or biological …

Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis

NES Tay, D Lehnherr, T Rovis - Chemical reviews, 2021 - ACS Publications
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

[HTML][HTML] Recent progress in cathodic reduction-enabled organic electrosynthesis: Trends, challenges, and opportunities

B Huang, Z Sun, G Sun - eScience, 2022 - Elsevier
Compared with general redox chemistry, electrochemistry using the electron as a potent,
controllable, yet traceless alternative to chemical oxidants/reductants usually offers more …

A guide to organic electroreduction using sacrificial anodes

Y Li, L Wen, W Guo - Chemical Society Reviews, 2023 - pubs.rsc.org
Organic electrosynthesis is a green strategy for the synthesis of valuable molecules.
Electrochemical reactions using sacrificial metal anodes enable new reactivity to be …

Modular terpene synthesis enabled by mild electrochemical couplings

SJ Harwood, MD Palkowitz, CN Gannett, P Perez… - Science, 2022 - science.org
The synthesis of terpenes is a large field of research that is woven deeply into the history of
chemistry. Terpene biosynthesis is a case study of how the logic of a modular design can …

Electroreductive Dicarboxylation of Unactivated Skipped Dienes with CO2

W Zhang, LL Liao, L Li, Y Liu, LF Dai… - Angewandte Chemie …, 2023 - Wiley Online Library
Carboxylation of easily available alkenes with CO2 is highly important to afford value‐added
carboxylic acids. Although dicarboxylation of activated alkenes, especially 1, 3‐dienes, has …

Interfacial Water Tuning by Intermolecular Spacing for Stable CO2 Electroreduction to C2+ Products

Z Liu, X Lv, S Kong, M Liu, K Liu… - Angewandte Chemie …, 2023 - Wiley Online Library
Electroreduction of CO2 to multi‐carbon (C2+) products is a promising approach for
utilization of renewable energy, in which the interfacial water quantity is critical for both the …

Counter electrode reactions—important stumbling blocks on the way to a working electro‐organic synthesis

M Klein, SR Waldvogel - Angewandte Chemie International …, 2022 - Wiley Online Library
Over the past two decades, electro‐organic synthesis has gained significant interest, both in
technical and academic research as well as in terms of applications. The omission of …

Achieving superior anticorrosion and antibiofouling performance of polyaniline/graphitic carbon nitride composite coating

F Guo, L Li, Y Shi, W Shi, X Yang, H Li - Progress in Organic Coatings, 2023 - Elsevier
Microorganisms sticking to the coating's surface might hasten its demise, and corrosive ions
are more capable of penetrating the coating-substrate contact, resulting in local corrosion of …

Comprehensive comparisons between directing and alternating current electrolysis in organic synthesis

L Zeng, J Wang, D Wang, H Yi… - Angewandte Chemie …, 2023 - Wiley Online Library
Organic electrosynthesis has consistently aroused significant interest within both academic
and industrial spheres. Despite the considerable progress achieved in this field, the majority …