[HTML][HTML] Spin state switching in iron coordination compounds

P Gütlich, AB Gaspar, Y Garcia - Beilstein journal of organic …, 2013 - beilstein-journals.org
The article deals with coordination compounds of iron (II) that may exhibit thermally induced
spin transition, known as spin crossover, depending on the nature of the coordinating ligand …

Structure: function relationships in molecular spin-crossover complexes

MA Halcrow - Chemical Society Reviews, 2011 - pubs.rsc.org
Spin-crossover compounds are becoming increasingly popular for device and sensor
applications, and in soft materials, that make use of their switchable colour, paramagnetism …

Triazole‐based one‐dimensional spin‐crossover coordination polymers

O Roubeau - Chemistry–A European Journal, 2012 - Wiley Online Library
One‐dimensional coordination FeII polymers constructed through triple N1, N2‐1, 2, 4‐
triazole bridges form a unique class of spin‐crossover materials, the synthetic versatility of …

Crystallography and spin-crossover. A view of breathing materials

P Guionneau - Dalton Transactions, 2014 - pubs.rsc.org
The spin-crossover phenomenon (SCO) is a fascinating field that potentially concerns any
material containing a (d4–d7) transition metal complex finding therefore an echo in as …

[HTML][HTML] Structural analysis of spin-crossover materials: From molecules to materials

E Collet, P Guionneau - Comptes Rendus Chimie, 2018 - Elsevier
In molecular spin-crossover materials, the spin-state switching is strongly coupled with
changes in the structural degrees of freedom, which play a central role in the alteration of …

Spin-crossover in iron (II)-Schiff base complexes

KS Kumar, Y Bayeh, T Gebretsadik, F Elemo… - Dalton …, 2019 - pubs.rsc.org
The spin-crossover (SCO) phenomenon is one of the most prominent examples of bi-stability
in molecular chemistry, and the SCO complexes are proposed for nanotechnological …

A critical review of the T (LIESST) temperature in spin crossover materials− What it is and what it is not

G Chastanet, C Desplanches, C Baldé… - Chemistry Squared …, 2018 - hal.science
Light-Induced Excited Spin-State Trapping has been studied since 1982 in solution and
1984 in solid state as it offers a reversible way of photoswitching the electronic configuration …

Large Thermal Hysteresis for Iron(II) Spin Crossover Complexes with N-(Pyrid-4-yl)isonicotinamide

C Lochenie, W Bauer, AP Railliet, S Schlamp… - Inorganic …, 2014 - ACS Publications
A new series of iron (II) 1D coordination polymers with the general formula [FeL1 (pina)]· x
solvent with L1 being a tetradentate N2O22–coordinating Schiff-base-like ligand [([3, 3′]-[1 …

Halogen Substitution Effects on N2O Schiff Base Ligands in Unprecedented Abrupt FeII Spin Crossover Complexes

W Phonsri, DS Macedo, KR Vignesh… - … A European Journal, 2017 - Wiley Online Library
A family of halogen‐substituted Schiff base iron (II) complexes,[FeII (qsal‐X) 2],(qsal‐X= 5‐X‐
N‐(8‐quinolyl) salicylaldimines)) in which X= F (1), Cl (2), Br (3) or I (4) has been …

Mapping the cooperativity pathways in spin crossover complexes

MG Reeves, E Tailleur, PA Wood, M Marchivie… - Chemical …, 2021 - pubs.rsc.org
Crystal packing energy calculations are applied to the [Fe (PM-L) 2 (NCS) 2] family of spin
crossover (SCO) complexes (PM-L= 4-substituted derivatives of the N-(2-pyridylmethylene) …