Determining the location and nature of the electron pairs within a molecule provides an
intuitive representation of electronic structures. Yet, most of the available theoretical …

The low-lying singlet states of biphenylene have been studied using ab initio methods.
Vertical excitation energies were calculated by multiconfigurational perturbation theory …

Biphenylene in various solvents is investigated by picosecond time-resolved absorption
spectroscopy. The time dependence of the spectral shape of the vibrationally hot S n← S 1 …

The resolution of chiral compounds into enantiomers by irradiation with circularly polarized
light is a clearly understood phenomenon. 1 If the two enantiomers of a compound are …

Biphenylene (BP) has been deemed to be a photoinert molecule because it fluoresces very
weakly, has little triplet transition, and does not react photochemically. 1 However, here we …

It is shown that the S 1↔ S 0 pure-electron transition frequencies of biphenylene absorption
and emission essentially differ. It follows from this and known photophysical characteristics …

Показано, что частоты чисто электронных вибронных переходов с поглощением и
испусканием между состояниями S 1 и S 0 у бифенилена существенно различаются. Из …

The TP absorption spectrum of crystalline biphenylene has been measured at 77 K in the
region of S 2. Vibronically induced transitions are observed due to b 3u vibrations and to …

1. Introduction luminescence 2, 3 of inorganic Reviews have appeared on the photophysics
of metal complexes, pressure effects on photochemical reactions, 4 photoredox reactions of …

In this thesis, original applications of the Density Overlap Region Indicator (DORI), a density
dependent bonding descriptor capable of simultaneously capturing covalent and …