X-ray absorption spectroscopy (XAS) today represents a widespread and powerful technique, able to monitor complex systems under in situ and operando conditions, while …
Although Ziegler–Natta (ZN) catalysts play a major role in the polyolefin market, a true understanding of their properties at the molecular level is still missing. In particular, there is a …
In this paper, which is the first part of a more extended work, we elucidate the molecular level structure of a highly active SiO 2-supported Ziegler-Natta precatalyst obtained by …
L Zhong, M Barreau, V Caps, V Papaefthimiou… - ACS …, 2021 - ACS Publications
Preferential oxidation of CO (COPrOx) is a catalytic reaction targeting the removal of trace amounts of CO from hydrogen-rich gas mixtures. Non-noble metal catalysts, such as Cu and …
L Zhong, M Barreau, D Chen, V Caps… - Applied Catalysis B …, 2021 - Elsevier
The preferential oxidation of CO in H 2-rich mixtures (COPrOx) is a major catalytic reaction utilized for hydrogen purification. In the exploration of alternatives to noble metals, cobalt …
Ce 3+ presence and formation in Ce-based UiO-66 Metal-Organic Framework (MOF) still presents a debated evaluation between the employed characterization techniques. In this …
The development of Ce-based materials is directly dependent on the catalyst surface defects, which is caused by the calcination steps required to increase structural stability. At …
This short review summarizes the main results achieved in the field of operando spectroscopies applied to heterogeneous catalysts for olefin polymerization. Following a …
S Rojas-Buzo, D Salusso, A Jouve, E Bracciotti… - Applied Catalysis B …, 2024 - Elsevier
Direct reaction of carbon dioxide and methanol to produce dimethylcarbonate (DMC) is an interesting process that allows the synthesis of such valuable product in a more …