The paper reviews data reported on the synthesis, molecular and electronic structure of
heterocyclic derivatives of low valent silicon, germanium, tin, and lead for the period from …

Anionic, metal‐centered nucleophiles are emerging compounds with unique reactivities.
Here, we describe the isolation and full characterization of the first tetraamido tin (II) dianion …

The biological applications of germylenes remain unrealised owing to their unstable nature.
We report the isolation of air‐, water‐, and culture‐medium‐stable germylene DPMGeOH (3; …

The synthesis and structure analysis of a series of mono and diylide‐substituted tetrylenes of
type YEX and Y2E (E= Ge, Sn, Pb; X= Cl or Br) using a thiophosphinoyl‐tethered metallated …

Although N‐heterocyclic phosphenium (NHP) cations have received considerable research
interest due to their application in organocatalysis, including asymmetric synthesis …

Dinuclear low‐valent compounds of the heavy main group elements are rare species owing
to their intrinsic reactivity. However, they represent desirable target molecules due to their …

The intramolecularly double‐donor‐stabilized stannylene 1 has been synthesized from the
salt‐metathesis reaction between two equivalents of lithium pyridine ene‐amide L1 and …

On the occasion to celebrate 130 years of ZAAC, we summarize about 20 years of our
journey through inorganic chemistry with “large” solids (single‐crystalline compounds) and …