Palladium/norbornene cooperative catalysis

J Wang, G Dong - Chemical reviews, 2019 - ACS Publications
Palladium/norbornene cooperative catalysis has emerged as a distinct approach to
construct polyfunctionalized arenes from readily available starting materials. This Review …

Palladium (II)‐Initiated Catellani‐Type Reactions

HG Cheng, S Chen, R Chen, Q Zhou - Angewandte Chemie, 2019 - Wiley Online Library
The Catellani reaction is known as a powerful strategy for the expeditious synthesis of highly
substituted arenes and benzo‐fused rings, which are usually difficult to access through …

Palladium/Norbornene‐Catalyzed Direct Vicinal Di‐Carbo‐Functionalization of Indoles: Reaction Development and Mechanistic Study

X Liu, Y Zhou, X Qi, R Li, P Liu… - Angewandte Chemie …, 2023 - Wiley Online Library
Methods that can simultaneously install multiple different functional groups to heteroarenes
via C− H functionalizations are valuable for complex molecule synthesis, which, however …

Structurally modified norbornenes: a key factor to modulate reaction selectivity in the palladium/norbornene cooperative catalysis

R Li, G Dong - Journal of the American Chemical Society, 2020 - ACS Publications
Palladium/norbornene (Pd/NBE) cooperative catalysis has received enormous attention and
found numerous synthetic applications in the past two decades. Considering the critical …

Recent progress on Catellani reaction

Z Chen, F Zhang - Tetrahedron, 2023 - Elsevier
The Catellani reaction is a palladium-catalyzed hydrocarbon-activated multicomponent
tandem reaction involving an aryl halide, an electrophilic coupling reagent and a terminating …

Catalytic Synthesis of Atropisomeric o-Terphenyls with 1,2-Diaxes via Axial-to-Axial Diastereoinduction

Q Gao, C Wu, S Deng, L Li, ZS Liu, Y Hua… - Journal of the …, 2021 - ACS Publications
Herein, we report a modular and convergent strategy for the assembly of atropisomeric o-
terphenyls with 1, 2-diaxes via palladium/chiral norbornene cooperative catalysis and axial …

[HTML][HTML] Pushing the boundaries of C–H bond functionalization chemistry using flow technology

S Govaerts, A Nyuchev, T Noel - Journal of Flow Chemistry, 2020 - Springer
C–H functionalization chemistry is one of the most vibrant research areas within synthetic
organic chemistry. While most researchers focus on the development of small-scale batch …

Modular dual-tasked C–H methylation via the Catellani strategy

Q Gao, Y Shang, F Song, J Ye, ZS Liu, L Li… - Journal of the …, 2019 - ACS Publications
We report a dual-tasked methylation that is based on cooperative palladium/norbornene
catalysis. Readily available (hetero) aryl halides (39 iodides and 4 bromides) and …

A Practical and Regioselective Strategy for Aromatic C–H Difunctionalization via Site-Selective C–H Thianthrenation

Z Zhang, X Chen, ZJ Niu, ZM Li, Q Li, WY Shi… - Organic …, 2024 - ACS Publications
Herein, we present a novel Catellani-type reaction that employed aryl-thianthrenium salts as
aryl substrates to trigger the subsequent palladium/norbornene cooperatively catalyzed …

Site‐Selective C− H Functionalization of Carbazoles

M Elsaid, R Ge, C Liu, D Maiti… - Angewandte Chemie …, 2023 - Wiley Online Library
Carbazole alkaloids hold great potential in pharmaceutical and material sciences. However,
the current approaches for C1 functionalization of carbazoles rely on the use of a pre …