[HTML][HTML] Bacteriochlorins and their metal complexes as NIR-absorbing photosensitizers: Properties, mechanisms, and applications

B Pucelik, A Sułek, JM Dąbrowski - Coordination Chemistry Reviews, 2020 - Elsevier
Bacterichlorins possess a characteristic intense electronic absorption in the near-infrared
part of the electromagnetic radiation (NIR) from 700 nm up to 900 nm, where endogenous …

Beyond green with synthetic chlorophylls–Connecting structural features with spectral properties

M Taniguchi, DF Bocian, D Holten… - Journal of Photochemistry …, 2022 - Elsevier
The distinct features of chlorophylls in photosynthesis have led to the formation of numerous
derivatives for applications encompassing solar energy conversion, molecular photonics …

Charge transfer as a mechanism for chlorophyll fluorescence concentration quenching

S Bourne-Worster, O Feighan… - Proceedings of the …, 2023 - National Acad Sciences
Highly concentrated solutions of chlorophyll display rapid fluorescence quenching. The
same devastating energy loss is not seen in photosynthetic light-harvesting antenna …

[HTML][HTML] Multidimensional electronic spectroscopy in high-definition—Combining spectral, temporal, and spatial resolutions

V Tiwari - The Journal of Chemical Physics, 2021 - pubs.aip.org
Over the past two decades, coherent multidimensional spectroscopies have been
implemented across the terahertz, infrared, visible, and ultraviolet regions of the …

Panchromatic chromophore–tetrapyrrole light-harvesting arrays constructed from Bodipy, perylene, terrylene, porphyrin, chlorin, and bacteriochlorin building blocks

G Hu, R Liu, EJ Alexy, AK Mandal, DF Bocian… - New Journal of …, 2016 - pubs.rsc.org
Panchromatic absorbers are potentially valuable for use in molecular-based energy-
conversion schemes. A prior dyad composed of a perylene-monoimide joined at the 9 …

Strongly coupled bacteriochlorin dyad studied using phase-modulated fluorescence-detected two-dimensional electronic spectroscopy

V Tiwari, YA Matutes, A Konar, Z Yu, M Ptaszek… - Optics express, 2018 - opg.optica.org
Fluorescence-detected two-dimensional electronic spectroscopy (F-2DES) projects the third-
order non-linear polarization in a system as an excited electronic state population which is …

Engineering giant excitonic coupling in bioinspired, covalently bridged BODIPY dyads

S Ansteatt, B Uthe, B Mandal, RS Gelfand… - Physical Chemistry …, 2023 - pubs.rsc.org
Strong excitonic coupling in photosynthetic systems is believed to enable efficient light
absorption and quantitative charge separation, motivating the development of artificial multi …

Tailoring Panchromatic Absorption and Excited-State Dynamics of Tetrapyrrole–Chromophore (Bodipy, Rylene) Arrays Interplay of Orbital Mixing and Configuration …

AK Mandal, JR Diers, DM Niedzwiedzki… - Journal of the …, 2017 - ACS Publications
Three sets of tetrapyrrole–chromophore arrays have been examined that exhibit
panchromatic absorption across large portions of the near-ultraviolet (NUV) to near-infrared …

Balancing Panchromatic Absorption and Multistep Charge Separation in a Compact Molecular Architecture

A Roy, NCM Magdaong, H Jing, J Rong… - The Journal of …, 2022 - ACS Publications
A panchromatic triad and a charge-separation unit are joined in a crossbar architecture to
capture solar energy. The panchromatic-absorber triad (T) is comprised of a central free …

Bacteriochlorin dyads as solvent polarity dependent near-infrared fluorophores and reactive oxygen species photosensitizers

NN Esemoto, Z Yu, L Wiratan, A Satraitis… - Organic letters, 2016 - ACS Publications
Symmetrical, near-infrared absorbing bacteriochlorin dyads exhibit gradual reduction of their
fluorescence (intensity and lifetime) and reactive oxygen species photosensitization …