Synthetic chlorins, possible surrogates for chlorophylls, prepared by derivatization of porphyrins

M Taniguchi, JS Lindsey - Chemical reviews, 2017 - ACS Publications
Chlorophylls make Earth green, are the central constituents in the engine of photosynthesis,
and not surprisingly have garnered immense attention. A chlorin, the core chromophore of a …

[HTML][HTML] Bacteriochlorins and their metal complexes as NIR-absorbing photosensitizers: Properties, mechanisms, and applications

B Pucelik, A Sułek, JM Dąbrowski - Coordination Chemistry Reviews, 2020 - Elsevier
Bacterichlorins possess a characteristic intense electronic absorption in the near-infrared
part of the electromagnetic radiation (NIR) from 700 nm up to 900 nm, where endogenous …

De Novo Synthesis of Gem-Dialkyl Chlorophyll Analogues for Probing and Emulating Our Green World

JS Lindsey - Chemical reviews, 2015 - ACS Publications
De Novo Synthesis of Gem-Dialkyl Chlorophyll Analogues for Probing and Emulating Our Green
World | Chemical Reviews ACS ACS Publications C&EN CAS Find my institution Log In …

Singlet and triplet excited state properties of natural chlorophylls and bacteriochlorophylls

DM Niedzwiedzki, RE Blankenship - Photosynthesis research, 2010 - Springer
Ten naturally occurring chlorophylls (a, b, c 2, d) and bacteriochlorophylls (a, b, c, d, e, g)
were purified and studied using the optical spectroscopic techniques of both steady state …

Accessing the near-infrared spectral region with stable, synthetic, wavelength-tunable bacteriochlorins

M Taniguchi, DL Cramer, AD Bhise, HL Kee… - New Journal of …, 2008 - pubs.rsc.org
The near-infrared (NIR) spectral region has been comparatively under-utilized for diverse
materials and medical applications owing to the lack of chromophores that afford stability …

Beyond green with synthetic chlorophylls–Connecting structural features with spectral properties

M Taniguchi, DF Bocian, D Holten… - Journal of Photochemistry …, 2022 - Elsevier
The distinct features of chlorophylls in photosynthesis have led to the formation of numerous
derivatives for applications encompassing solar energy conversion, molecular photonics …

51 photochemistry of chlorophylls and their synthetic analogs

H Tamiaki, M Kunieda - Handbook of Porphyrin Science (Volume 11 …, 2011 - World Scientific
The following sections are included: List of Abbreviations I. Introduction II. Characterization
of Chlorophylls A. Structures and Nomenclature B. Light Absorption III. Natural Chlorophylls …

Photophysical properties and electronic structure of stable, tunable synthetic bacteriochlorins: extending the features of native photosynthetic pigments

E Yang, C Kirmaier, M Krayer… - The Journal of …, 2011 - ACS Publications
Bacteriochlorins, which are tetrapyrrole macrocycles with two reduced pyrrole rings, are
Nature's near-infrared (NIR) absorbers (700–900 nm). The strong absorption in the NIR …

The fluorescence quantum yield parameter in Förster resonance energy transfer (FRET)—Meaning, misperception, and molecular design

JS Lindsey, M Taniguchi, DF Bocian… - Chemical Physics …, 2021 - pubs.aip.org
The fluorescence quantum yield parameter in Förster resonance energy transfer (FRET)
processes underpins vital phenomena ranging from light harvesting in photosynthesis to …

Hydrogen evolution catalysis by a sparsely substituted cobalt chlorin

AG Maher, G Passard, DK Dogutan, RL Halbach… - ACS …, 2017 - ACS Publications
A sparsely substituted chlorin macrocycle containing a Co (II) center (1-Co) has been
synthesized and structurally characterized. The Co (II) atom resides in a square planar …