Flash vacuum pyrolysis (FVP) of azides is an extremely valuable method of generating
nitrenes and studying their thermal rearrangements. The nitrenes can in many cases be …

Flash vacuum pyrolysis (FVP) had its beginnings in the 1940s and 1950s, mainly through
mass spectrometric detection of pyrolytically formed free radicals. In the 1960s many organic …

Surface chemistry mediated direct optical patterning represents an emerging strategy for
incorporating colloidal nanocrystals (NCs) in integrated optoelectronic platforms including …

Vinyl pnictinidenes are an elusive family of molecules that have been suggested as key
intermediates in multiple chemical reactions and commonly display a predisposition toward …

Carbenes and nitrenes are key intermediates involved in numerous chemical processes,
and they have attracted considerable attention in synthetic chemistry, biochemistry, and …

Triplet carbenes and triplet molecular oxygen can combine to form singlet carbonyl O-oxide
Criegee intermediates in an overall spin-allowed transformation. While this reaction runs at …

Abstract Dative Bond (IUPAC):“The coordination bond formed upon interaction between
molecular species, one of which serves as a donor and the other as an acceptor of the …

Imidogen (NH) is the simplest nitrogen hydride that plays an important role in combustion
and interstellar chemistry, and its combination with H2O is the prototypical amidation …

Quantum mechanical tunneling of heavy‐atoms and vibrational excitation chemistry are
unconventional and scarcely explored types of reactivity. Once fully understood, they might …

Triplet phenylphosphinidene was prepared by light-induced elimination of ethylene from the
corresponding phenylphosphirane and was characterized by IR and UV/vis spectroscopy …