CW Frank, V Rao, MM Despotopoulou, RFW Pease… - Science, 1996 - science.org
The molecular organization in ultrathin polymer films (thicknesses less than 1000 angstroms) and thin polymer films (thicknesses between 1000 and 10,000 angstroms) may …
JH van Zanten, WE Wallace, W Wu - Physical Review E, 1996 - APS
The thermal behavior of ultrathin films of poly-(2)-vinylpyridine spin-cast on acid-cleaned silicon oxide substrates is considered. The interaction between the polymer and the …
S Kawana, RAL Jones - Physical Review E, 2001 - APS
We have used ellipsometry to study the thermal expansivity of thin polystyrene films on silicon substrates with thicknesses of 10–200 nm. We find well-defined glass transitions, and …
The physical aging at 35° C of three glassy polymers, polysulfone, a polyimide and poly (2, 6- dimethyl-1, 4-phenylene oxide), has been tracked by measurement of the permeation of …
WE Wallace, JH van Zanten, WL Wu - Physical review E, 1995 - APS
The thermal expansion of polystyrene thin films, supported on hydrogen-terminated silicon substrates, is measured by x-ray reflectivity. Films on the order of 400 Å and thinner show no …
A combination of dynamic shear rheology, thermomechanical analysis (TMA), scanning electron microscopy (SEM), Near-Edge X-ray Absorption Fine Structure (NEXAFS), and …
In this paper the glass transition temperature (T g) in thin polymer films has been studied. Ellipsometry has been used to measure T g of poly (α-methylstyrene)(PAMS) thin films as a …
The glass transition temperature (T g) in the thin poly (α-methyl styrene) and polysufone films that are coated on the surface of a Si wafer is investigated in this paper. A novel …
Temperature-ramping anisotropy measurements were used to probe the molecular mobility of fluorescent probes in polystyrene, poly (methyl methacrylate), and poly (2-vinyl pyridine) …