6 Studies of spin-coated polymer films

K Norrman, A Ghanbari-Siahkali… - Annual Reports Section" C …, 2005 - pubs.rsc.org
Spin-coating is widely employed for the highly reproducible fabrication of thin film coatings
over large areas with high structural uniformity. Research in recent years has extended the …

Structure in thin and ultrathin spin-cast polymer films

CW Frank, V Rao, MM Despotopoulou, RFW Pease… - Science, 1996 - science.org
The molecular organization in ultrathin polymer films (thicknesses less than 1000
angstroms) and thin polymer films (thicknesses between 1000 and 10,000 angstroms) may …

Effect of strongly favorable substrate interactions on the thermal properties of ultrathin polymer films

JH van Zanten, WE Wallace, W Wu - Physical Review E, 1996 - APS
The thermal behavior of ultrathin films of poly-(2)-vinylpyridine spin-cast on acid-cleaned
silicon oxide substrates is considered. The interaction between the polymer and the …

Character of the glass transition in thin supported polymer films

S Kawana, RAL Jones - Physical Review E, 2001 - APS
We have used ellipsometry to study the thermal expansivity of thin polystyrene films on
silicon substrates with thicknesses of 10–200 nm. We find well-defined glass transitions, and …

Physical aging of thin glassy polymer films monitored by gas permeability

Y Huang, DR Paul - Polymer, 2004 - Elsevier
The physical aging at 35° C of three glassy polymers, polysulfone, a polyimide and poly (2, 6-
dimethyl-1, 4-phenylene oxide), has been tracked by measurement of the permeation of …

Influence of an impenetrable interface on a polymer glass-transition temperature

WE Wallace, JH van Zanten, WL Wu - Physical review E, 1995 - APS
The thermal expansion of polystyrene thin films, supported on hydrogen-terminated silicon
substrates, is measured by x-ray reflectivity. Films on the order of 400 Å and thinner show no …

Investigation of the thermal, mechanical, and fracture properties of alumina–epoxy composites

LM McGrath, RS Parnas, SH King, JL Schroeder… - Polymer, 2008 - Elsevier
A combination of dynamic shear rheology, thermomechanical analysis (TMA), scanning
electron microscopy (SEM), Near-Edge X-ray Absorption Fine Structure (NEXAFS), and …

Thickness dependence of the glass transition temperature in thin polymer films

JH Kim, J Jang, WC Zin - Langmuir, 2001 - ACS Publications
In this paper the glass transition temperature (T g) in thin polymer films has been studied.
Ellipsometry has been used to measure T g of poly (α-methylstyrene)(PAMS) thin films as a …

Estimation of the thickness dependence of the glass transition temperature in various thin polymer films

JH Kim, J Jang, WC Zin - Langmuir, 2000 - ACS Publications
The glass transition temperature (T g) in the thin poly (α-methyl styrene) and polysufone
films that are coated on the surface of a Si wafer is investigated in this paper. A novel …

Molecular mobility in supported thin films of polystyrene, poly (methyl methacrylate), and poly (2-vinyl pyridine) probed by dye reorientation

K Paeng, R Richert, MD Ediger - Soft Matter, 2012 - pubs.rsc.org
Temperature-ramping anisotropy measurements were used to probe the molecular mobility
of fluorescent probes in polystyrene, poly (methyl methacrylate), and poly (2-vinyl pyridine) …