Ferrocenyl skeletons tagged with a variety of donor atoms (metalloligands) have become
popular in modern metal-catalyzed organic transformations, broadening the applications …

Amidation reactions of ferrocene phosphinocarboxylic acids and various simple or functional
amines provide access to a range of specific metalloligands combining the soft phosphine …

Sulfonation of (diphenylphosphinothioyl) ferrocene (1) with chlorosulfonic acid in acetic
anhydride affords the crude sulfonic acid Ph2P (S) fcSO3H (2; fc= ferrocene-1, 1′-diyl) …

A highly efficient catalytic system based on Pd (OAc) 2 and an imidazole-hydrazone ligand
has been developed for Suzuki–Miyaura cross-coupling reaction in water under aerobic …

Catalysis has been at the forefront of the developments that has revolutionised synthesis
and provided the impetus in the discovery of platform technologies for efficient C− C or C− X …

Anionic phosphinoferrocene amidosulfonates bearing sterically demanding tert-butyl
substituents in positions 3 and 3′ of the ferrocene scaffold, viz. rac-(Et3NH)[Fe (η5-t …

A simple approach for the intramolecular aroylation of electron-rich arenes under mild
conditions has been developed. A pH-controlled polarity umpolung strategy can be used to …

1′-(Diphenylphosphino) ferrocene-1-sulfonic acid (HL), isolated from the salt (Et3NH) L on
an ion exchanger, reacts with Rh (I) complexes [Rh (acac)(CO)(PR3)](acac= acetylacetonato …

The synthesis and characterization of three novel ferrocenylphosphino sulfonates, namely
[(η 5-C 5 H 3 PR 2 (SO 3 i-Pr)) Fe (η 5-C 5 H 5)](R= Ph, p-Tol, Cy), is presented along with …

A general challenging issue in the synthesis of hemilabile ferrocene ligands is the access to
highly functionalized ferrocene starting materials. These can bear donor/acceptor atoms …