Dissolution-DNP is a method to create solutions of molecules with nuclear spin polarization
close to unity. The many orders of magnitude signal enhancement have enabled many new …

The magnetic interactions between the nuclear magnetic moment and the magnetic moment
of unpaired electron (s) depend on the structure and dynamics of the molecules where the …

Nuclear magnetic resonance (NMR) spectroscopy is a powerful method to study the
molecular structure and dynamics of materials. The inherently low sensitivity of NMR …

[1-13C] pyruvate is the most widely used hyperpolarized metabolic magnetic resonance
imaging agent. Using a custom-built 7.0 T polarizer operating at 1.0 K and trityl radical …

Here, we present an integrated experimental and theoretical study of 1H dynamic nuclear
polarization (DNP) of a frozen aqueous glass containing free radicals at 7 T, under static …

The discovery of a truncated cross-effect (CE) in dynamic nuclear polarization (DNP) NMR
that has the features of an Overhauser-effect DNP (OE-DNP) is reported here. The apparent …

We discuss conceptual and instrumental progress in dissolution DNP since its introduction
in 2003. In our view there are three critical steps in the dissolution DNP process:(i) The …

In this chapter, we have attempted to present a comprehensive description of the spin
dynamics leading to the nuclear signal enhancements observed during dynamic nuclear …

We characterize the effect of specifically bound biradicals on the NMR spectra of
dihydrofolate reductase from E. coli. Dynamic nuclear polarization methods enhance the …

Protein solid-state NMR has evolved dramatically over the last two decades, with the
development of new hardware and sample preparation methodologies. This technique is …