Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

The catalytic functionalization of unreactive C− H bonds has recently brought a revolution in
synthetic methodologies for the production of pharmaceuticals and natural products and for …

Although machine learning bears enormous potential to accelerate developments in
homogeneous catalysis, the frequent need for extensive experimental data can be a …

Abstract In 2010, Richard Heck, Ei‐ichi Negishi, and Akira Suzuki joined the prestigious
circle of Nobel Laureate chemists for their roles in discovering and developing highly …

Despite the widespread application of Suzuki-Miyaura cross-coupling to forge carbon-
carbon bonds, the structure of the reactive intermediates underlying the key transmetalation …

Self‐replication is a fundamental concept. The idea of an entity that can repeatedly create
more of itself has captured the imagination of many thinkers from von Neumann to …

Abstract Im Jahr 2010 wurden Richard Heck, Ei‐ichi Negishi und Akira Suzuki in den
illustren Kreis der Chemie‐Nobelpreisträger aufgenommen. Begründet wurde diese …

Kinetic data for the C–H bond activation of 2-phenylpyridine by RuII (carboxylate) 2 (p-
cymene) I (acetate) and I′(pivalate) are available for the first time. They reveal an …

The importance of autocatalysis spans from practical applications such as in chemically
amplified photoresists, to autocatalysis playing a fundamental role in evolution as well as a …

Dinuclear PdI complexes have found widespread applications as diverse catalysts for a
multitude of transformations. Initially their ability to function as pre‐catalysts for low …