Chiral phosphoric acids (CPAs) have been used as efficient organocatalysts since the first
examples were reported 18 years ago by Akiyama and Terada. Although they were …

Catalytic generation of ambiphilic π-allyl–metal complexes and their utility in
enantioselective transformations constitutes a powerful approach for introduction of allyl …

Cu-catalyzed highly stereoselective and enantiodivergent syntheses of (Z)-or (E)-β, γ-
unsaturated ketones from 1, 3-butadienyl silanes are developed. The nature of the silyl …

Stereoconvergent reactions enable the transformation of mixed stereoisomers into well-
defined, chiral products─ a crucial strategy for handling Z/E-mixed olefins, which are …

We report herein a Cu‐catalyzed regio‐, diastereo‐and enantioselective acylboration of 1, 3‐
butadienylboronate with acyl fluorides. Under the developed conditions, the reactions …

The development of α, α-disubstituted crotylboronate reagents is reported. Chiral Brønsted
acid-catalyzed asymmetric aldehyde addition with the developed E-crotylboron reagent …

We present herein an unprecedented desymmetrization of meso 1, 3-diones by
enantioselective intermolecular condensation. Under the catalysis by a chiral phosphoric …

We report herein the development of stereodivergent syntheses of enantioenriched
homoallylic alcohols using chiral nonracemic α‐CH2Bpin‐substituted crotylboronate. Chiral …

We report herein a rare example of enantiodivergent aldehyde addition with β‐alkenyl allylic
boronates via chiral Brønsted acid catalysis. 2, 6‐Di‐9‐anthracenyl‐substituted chiral …

Stereo-and enantioselective syntheses of 1, 2-oxaborinan-3-enes and δ-boryl-substituted
homoallylic alcohols are reported. We developed a practical approach to synthesize α-boryl …