Anion effects on spin crossover systems: from supramolecular chemistry to magnetism

SZ Zhao, HW Zhou, CY Qin, HZ Zhang… - … A European Journal, 2023 - Wiley Online Library
The field of anion supramolecular chemistry has received more and more attention in recent
years. Anions with diverse types and geometries have been widely used for the synthesis of …

Stimuli-responsive magnetic materials: impact of spin and electronic modulation

K Kaushik, S Mehta, M Das, S Ghosh… - Chemical …, 2023 - pubs.rsc.org
Addressing molecular bistability as a function of external stimuli, especially in spin-crossover
(SCO) and metal-to-metal electron transfer (MMET) systems, has seen a surge of interest in …

Homochiral Mn3+ Spin-Crossover Complexes: A Structural and Spectroscopic Study

IA Kühne, A Ozarowski, A Sultan, K Esien… - Inorganic …, 2022 - ACS Publications
Structural, magnetic, and spectroscopic data on a Mn3+ spin-crossover complex with Schiff
base ligand 4-OMe-Sal2323, isolated in crystal lattices with five different counteranions, are …

Optical phenomena in molecule-based magnetic materials

JJ Zakrzewski, M Liberka, J Wang, S Chorazy… - Chemical …, 2024 - ACS Publications
Since the last century, we have witnessed the development of molecular magnetism which
deals with magnetic materials based on molecular species, ie, organic radicals and metal …

Reverse Hofmann-type spin-crossover compound showing a multichannel controllable color change in an ambient environment

JH Yang, YX Zhao, JP Xue, ZS Yao, J Tao - Inorganic Chemistry, 2021 - ACS Publications
Materials that demonstrate a multichannel controllable color change in response to external
stimuli are fascinating for their potential applications in sensoring and displaying devices …

Structure–function correlations in mononuclear manganese (iii) spin crossover systems with a big conjugated hexadentate Schiff-base ligand

SZ Zhao, CY Qin, S Wang, M Yamashita, YH Li… - Dalton …, 2020 - pubs.rsc.org
This paper reports the syntheses, crystal structures and magnetic properties of spin
crossover (SCO) salts of formulae [Mn (naphth-sal-N-1, 5, 8, 12)] SbF6 (1),[Mn (naphth-sal-N …

Pyridine-based complexes of copper (II) chloride and bromide: ligand conformation effects on crystal structure. Synthesis, structure and magnetic behavior of Cu (2-Cl …

RJ Dubois, CP Landee, M Rademeyer… - Journal of …, 2019 - Taylor & Francis
Reaction of copper (II) chloride or bromide with 2-chloro-3-bromopyridine or 2, 3-
dichloropyridine generates a family of compounds of the general formula L 2 CuX 2 (1–4). X …

Polymer optical waveguide sensor based on Fe-Amino-Triazole complex molecular switches

MS Khan, H Farooq, C Wittmund, S Klimke… - Polymers, 2021 - mdpi.com
We report on a polymer-waveguide-based temperature sensing system relying on
switchable molecular complexes. The polymer waveguide cladding is fabricated using a …

Hydrogen-bonded assemblies of iron (ii) spin crossover complexes

V Jornet-Mollá, MI Rodríguez-Tarrazó… - Dalton …, 2024 - pubs.rsc.org
The paper reports on the synthesis, crystal structure, thermal and magnetic properties of spin
crossover (SCO) salts containing the [Fe (bpp) 2] 2+ cation (bpp= 2, 6-bis (pyrazol-3-yl) …

Pressure-Induced Phase Transition in Mn(Ta,Nb)2O6: An Experimental Investigation and First-Principle Study

Y Liu, S Huang, X Li, H Song, J Xu, D Zhang… - Inorganic …, 2020 - ACS Publications
The high-pressure and high-temperature behaviors of manganotantalite Mn (Ta, Nb) 2O6
have been investigated by single-crystal X-ray diffraction and Raman spectroscopy …