Theoretical study of the reaction of hydrogen atoms with three pentene isomers: 2-methyl-1-butene, 2-methyl-2-butene, and 3-methyl-1-butene

J Power, KP Somers, SS Nagaraja… - The Journal of …, 2020 - ACS Publications
This paper presents a comprehensive potential energy surface (PES) for hydrogen atom
addition to and abstraction from 2-methyl-1-butene, 2-methyl-2-butene, and 3-methyl-1 …

Isomeric effects on the reactivity of branched alkenes: An experimental and kinetic modeling study of methylbutenes

H Song, D Kang, G Fioroni, G Kukkadapu… - Combustion and …, 2023 - Elsevier
A detailed experimental study of the low-to-intermediate temperature combustion of
methylbutene isomers, ie, branched C 5 alkenes, has been undertaken with multiple …

Shock-tube spectroscopic CO and H2O measurements during 2-methyl-1-butene combustion and chemical kinetics modeling

CM Grégoire, CK Westbrook, G Kukkadapu… - Combustion and …, 2022 - Elsevier
Abstract New CO and H 2 O time histories were measured for 2-Methyl-1-Butene (2M1B)
behind reflected shock waves. The experimental setup was developed to simultaneously …

DME-Propane Ignition Delay Time Measurements at Mixing Controlled Compression Ignition Engine-Relevant Conditions

ZP Mohammed, RK Rahman, M Pierro, J Urso, S Vasu - 2023 - sae.org
The blend of dimethyl ether (DME, CH3OCH3) and propane (C3H8) is a potentially
renewable fuel mixture that has the potential to replace diesel in compression ignition …

Experimental and kinetic modeling study on the ignition characteristics of methyl acrylate and vinyl acetate: Effect of CC double bond

C Li, Z Zhang, L He, M Ye, H Ning, Y Shang, J Shi… - Energy, 2022 - Elsevier
The ignition characteristics of methyl acrylate (MA) and vinyl acetate (VA) are investigated in
a heated shock tube at 1176–1618 K, 4–16 atm, and equivalence ratios of 0.5–2.0. The …

Direct measurement of reaction rate for decomposition of diisopropyl methylphosphonate at high temperature using shock tube and laser absorption

RK Rahman, J Higgs, E Ninnemann… - … Journal of Chemical …, 2022 - Wiley Online Library
Diisopropyl methylphosphonate (DIMP) is an organophosphorus compound used as a
simulant for the chemical weapon Sarin. One of the means of destruction of Sarin is …

Laminar Flame Speed, Ignition Delay Time, and CO Laser Absorption Measurements of a Gasoline-like Blend of Pentene Isomers

CM Grégoire, CK Westbrook, SP Cooper… - The Journal of …, 2023 - ACS Publications
The combustion properties of a gasoline-like blend of pentene isomers were determined
using multiple types of experimental measurements. The representative mixture (Mix A) is …

A shock-tube and chemical kinetics model investigation encompassing all five pentene isomers

CM Grégoire, CK Westbrook, O Mathieu, SP Cooper… - Fuel, 2022 - Elsevier
Kinetic treatment of the full group of C5 olefins is presented with new measurements on 1-
pentene (1-C 5 H 10), 2-pentene (2-C 5 H 10), and 3-Methyl-1-Butene (3M1B) combined …

An experimental and master-equation modeling study of the kinetics of the reaction between resonance-stabilized (CH 3) 2 CCHCH 2 radical and molecular oxygen

SP Joshi, TT Pekkanen, P Seal, RS Timonen… - Physical Chemistry …, 2021 - pubs.rsc.org
The kinetics of the reaction between resonance-stabilized (CH3) 2CCHCH2 radical (R) and
O2 has been investigated using photoionization mass spectrometry, and master equation …

Experimental and kinetic modeling studies of isoprene pyrolysis at low and atmospheric pressures

G Chen, W Ding, Z Cheng, J Wang, L Xing, W Li… - Combustion and …, 2022 - Elsevier
Abstract Isoprene (2-methyl-1, 3-butadiene) is not only the main component in gasoline and
a potential fuel additive, but also is considered an important precursor of polycyclic aromatic …