ResponZIF structures: zeolitic imidazolate frameworks as stimuli-responsive materials

P Iacomi, G Maurin - ACS Applied Materials & Interfaces, 2021 - ACS Publications
Zeolitic imidazolate frameworks (ZIFs) have long been recognized as a prominent subset of
the metal–organic framework (MOF) family, in part because of their ease of synthesis and …

Neutron instruments for research in coordination chemistry

ZL Xue, AJ Ramirez‐Cuesta, CM Brown… - European Journal of …, 2019 - Wiley Online Library
Neutron diffraction and spectroscopy offer unique insight into structures and properties of
solids and molecular materials. All neutron instruments located at the various neutron …

[HTML][HTML] Post-synthetic ligand exchange as a route to improve the affinity of ZIF-67 towards CO2

D Villalgordo-Hernández, MA Diaz-Perez… - Chemical Engineering …, 2023 - Elsevier
Abstract The Zeolitic Imidazolate Framework 67 (ZIF-67) is a highly promising material
owing to its exceptional thermal stability, large specific surface area, cost-effectiveness, and …

Highly-Controlled Soft-Templating Synthesis of Hollow ZIF-8 Nanospheres for Selective CO2 Separation and Storage

FS Butt, A Lewis, R Rea, NA Mazlan… - … Applied Materials & …, 2023 - ACS Publications
Global warming is an ever-rising environmental concern, and carbon dioxide (CO2) is
among its major causes. Different technologies, including adsorption, cryogenic separation …

Leaching in Specific Facets of ZIF-67 and ZIF-L Zeolitic Imidazolate Frameworks During the CO2 Cycloaddition with Epichlorohydrin

JJ Delgado-Marín, A Rendón-Patiño… - Chemistry of …, 2023 - ACS Publications
Zeolitic imidazolate frameworks (ZIFs) have been profusely used as catalysts for inserting
CO2 into organic epoxides (ie, epichlorohydrin) through cycloaddition. Here, we …

H2, N2, CO2, and CH4 Unary Adsorption Isotherm Measurements at Low and High Pressures on Zeolitic Imidazolate Framework ZIF-8

J Hwang, H Azzan, R Pini, C Petit - Journal of Chemical & …, 2022 - ACS Publications
Excess adsorption of CO2, CH4, N2, and H2 on ZIF-8 was measured gravimetrically in the
pressure range ranging from vacuum to 30 MPa at 298.15, 313.15, 333.15, 353.15, and …

Crystal engineering of metal–organic framework thin films for gas separations

DJ Babu, G He, LF Villalobos… - … Sustainable Chemistry & …, 2018 - ACS Publications
Metal–organic frameworks or MOFs have witnessed a phenomenal rise owing to a highly
tunable synthetic chemistry allowing flexibility in the selection of its constituents, namely …

Understanding the breathing phenomena in nano-ZIF-7 upon gas adsorption

C Cuadrado-Collados, J Fernández-Català… - Journal of Materials …, 2017 - pubs.rsc.org
Synchrotron X-ray diffraction and inelastic neutron scattering measurements have been
applied to evaluate the breathing phenomena in small nanocrystals of ZIF-7 upon gas …

Elucidating correlated defects in metal organic frameworks using theory-guided inelastic neutron scattering spectroscopy

LSR Cavalcante, MA Dettmann, T Sours, D Yang… - Materials …, 2023 - pubs.rsc.org
Metal organic frameworks (MOFs) that incorporate metal oxide cluster nodes, exemplified by
UiO-66, have been widely studied, especially in terms of their deviations from the ideal …

Gate Opening Induced High Pore Volume Expansion in Flexible Zeolitic Imidazole Frameworks during CO2 Adsorption: A Direct Observation Using Positron …

J Mor, P Utpalla, S Mukherjee… - The Journal of …, 2023 - ACS Publications
Although Z eolitic I midazolate F rameworks (ZIFs) show a great promise in the field of
molecular separation owing to their crystalline morphology of pores, the sieving …