Redox‐active BIAN‐based Diimine Ligands in Metal‐Catalyzed Small Molecule Syntheses

J Bernauer, J Pölker, A Jacobi von Wangelin - ChemCatChem, 2022 - Wiley Online Library
Abstract α‐Diimine ligands have significantly shaped the coordination chemistry of most
transition metal complexes. Among them, bis (imino) acenaphthene ligands (BIANs) have …

Synthesis, properties, and catalysis of p-block complexes supported by bis (arylimino) acenaphthene ligands

J Wang, HS Soo, F Garcia - Communications Chemistry, 2020 - nature.com
Abstract Bis (arylimino) acenaphthene (Ar-BIAN) ligands have been recognized as robust
scaffolds for metal complexes since the 1990 s and most of their coordination chemistry was …

Hydrophobic Metal Halide Perovskites for Visible‐Light Photoredox C− C Bond Cleavage and Dehydrogenation Catalysis

Z Hong, WK Chong, AYR Ng, M Li… - Angewandte Chemie …, 2019 - Wiley Online Library
Two‐dimensional lead and tin halide perovskites were prepared by intercalating the long
alkyl group 1‐hexadecylammonium (HDA) between the inorganic layers. We observed …

Artificial photosynthesis by light absorption, charge separation, and multielectron catalysis

M Đokić, HS Soo - Chemical Communications, 2018 - pubs.rsc.org
Our society's current energy demands are largely met by the exploitation of fossil fuels,
which are unsustainable and environmentally harmful resources. However, Nature has …

Spectroscopic characterization and mechanistic studies on visible light photoredox carbon–carbon bond formation by bis (arylimino) acenaphthene copper …

YY Ng, LJ Tan, SM Ng, YT Chai, R Ganguly, Y Du… - ACS …, 2018 - ACS Publications
Currently, the most popular molecular photosensitizers used for synthetic organic chemistry
and energy applications are still the noble-metal-based ruthenium and iridium complexes …

The forgotten reagent of photoredox catalysis

TU Connell - Dalton Transactions, 2022 - pubs.rsc.org
Visible light powers an ever-expanding suite of reactions to both make and break chemical
bonds under otherwise mild conditions. As a reagent in photochemical synthesis, light is …

Aromatic β‐Diketone as a Novel Anchoring Ligand in Iridium (III) Complexes for Dye‐Sensitized Solar Cells

SI Bezzubov, IS Zharinova… - European Journal of …, 2020 - Wiley Online Library
A novel β‐diketone ligand bearing a thiophene moiety and an anchoring Ph‐COOCH3 unit
has been designed, prepared and used in synthesis of cyclometalated benzimidazole …

Pushing the Ag-loading of CO2 electrolyzers to the minimum via molecularly tuned environments

K Pellumbi, D Krisch, C Rettenmaier, H Awada… - Cell Reports Physical …, 2023 - cell.com
Electrochemically converting CO 2 to renewable synthons is steadily becoming a globally
scalable and important CO 2 utilization technology. Nevertheless, most industrial endeavors …

Tailoring the π-system of benzimidazole ligands towards stable light-harvesting cyclometalated iridium (iii) complexes

SV Tatarin, DE Smirnov, IV Taydakov, MT Metlin… - Dalton …, 2023 - pubs.rsc.org
The synthesis, structure, optical and redox properties as well as photovoltaic studies of
iridium (III) complexes with cyclometalated 2-arylbenzimidazoles decorated with various …

Rich redox-activity and solvatochromism in a family of heteroleptic cobalt complexes

VL Nadurata, MA Hay, JT Janetzki, GK Gransbury… - Dalton …, 2021 - pubs.rsc.org
The combination of redox-active metals with redox-active ligands can lead to interesting
charge transfer behaviours, including valence tautomerism and solvatochromism. With the …