Catalytic olefin metathesis has quickly emerged as one of the most often‐used
transformations in modern chemical synthesis. One class of catalysts that has led the way to …

The first “high oxidation state” transition metal complexes that contain a multiple metal-
carbon bond were discovered∼ 25 years ago in the form of (η5-C5H5) 2Ta (CH2)(CH3) 1 …

Mechanistic and synthetic studies in organometallic chemistry have provided considerable
insight into olefin metathesis and Ziegler-Natta polymerization. New homogeneous olefin …

Carbene Chemistry Page 1 Page 2 Carbene Chemistry FROM FLEETING
INTERMEDIATES TO POWERFUL REAGENTS Edited by Guy Bertrand Page 3 ISBN 0-203-91092-3 …

The first alkylidene complex in which the metal can be said to have a d0 electron
configuration (counting the alkylidene ligand as a dianion) was discovered in 1974 (1) …

Die katalytische Olefinmetathese hat sich schnell zu einer der am häufigsten eingesetzten
Transformationen der modernen chemischen Synthese entwickelt. Ein Klasse von …

Recent advances in olefin metathesis studies include the preparation of catalysts “in situ,”
supported catalysts, and tungsten-based catalysts, and observation of molybdacyclobutane …

Various metallabenzene complexes, analogues of benzene where one CH unit has been
replaced by an organometallic fragment, have been reported in the literature. A detailed …

Complex 1 and related tetracoordinate molybdenum alkylidenes developed by Schrock and
co-workers range amongst the most powerful alkene metathesis catalysts known to date.[1 …

Cationic RuII carbene complexes with tBu2PCH2PtBu2 (dtbpm) as a chelating ligand, which
are accessible by chloride abstraction from neutral precursors [(κ2‐dtbpm) Cl2Ru= CHR] …