The application of the Nicholas reaction chemistry of 2, 7-dioxygenated naphthalenes in the
synthesis of cyclohepta [de] napthalenes and in the synthesis of (±)-microstegiol (1) is …

Results are reported on the regioselective C‐deuteration of a series of related acyclic and
exocyclic enolates derived from substituted aryl ketones. We comment on factors, such as …

The total synthesis of the 9, 11-seco-rosane diterpene velloziolide (1) has been
accomplished by employing the Nicholas reaction chemistry of 2a as a γ-carbonyl cation …

(E)-Configurated allylic ligands (S)-6a− f and (S)-8, bearing a leaving group at C (3)(allylic
position) and an electron acceptor substituent at C (1), were synthesized from enantiopure …

This Account describes our work on highly electrophilic γ-carbonyl cations featuring
propargyldicobalt cations, cycloheptynedicobalt complexes, and the interconnection …

Efficient and enantiocontrolled synthesis of γ-hydroxy-α, β-unsaturated sulfones and esters
are reported through the reaction of enantioenriched α-selenyl aldehydes with EWG …

A general synthetic approach, capable of accessing a diverse range of 3, 3-disubstituted
quinoline-2, 4-diones and 1, 8-naphthyridine-2, 4-diones via titanium tetrachloride catalyzed …

The products corresponding to the reactions of arenes and γ-carbonyl cations may be
obtained by a one-pot, bicatalytic process involving InCl 3-catalyzed arene allylation and …

The generation of ε-carbonyl cations and their reactions with nucleophiles is accomplished
readily without transition metal cation stabilization, using the ε-bromide dienoate or dienone …

Abstract Nicholas reactions on 2, 7-dioxygenated naphthalenes give C-1 monosubstitution
and C-1/C-8 disubstitution in most cases. From γ-carbonyl cation monocondensation …