High-valent iron-oxo species are ubiquitous in nature and are present at the active site of
several metalloenzymes which perform challenging organic transformations. Mimicking …

Previous biomimetic studies clearly proved that equatorial ligands significantly influence the
redox potential and thus the stability/reactivity of biologically important oxoiron …

Reported are the synthesis and detailed studies of the iron (IV)-tosylimido complexes of two
isomeric pentadentate bispidine ligands (bispidines are 3, 7-diazabicyclo [3.3. 1] nonane …

Understanding the comparative oxidative abilities of high-valent metal-oxo/hydroxo/
hydroperoxo species holds the key to robust biomimic catalysts that perform desired organic …

Metal-oxo species are ubiquitous in nature and play a pivotal role in various biological
functions. While the popular Fe IV= O/NTs species have been studied in detail over the …

High-valent metal–oxo species have been characterised as key intermediates in both heme
and non-heme enzymes that are found to perform efficient aliphatic hydroxylation …

ArIO (ArI= 2-(tBuSO2) C6H4I) is an oxidant used to oxidize FeII species to their FeIV-oxo
state, enabling hydrogen-atom transfer (HAT) and oxygen-atom transfer (OAT) reactions at …

Iodosilarene derivatives (PhIO, PhI (OAc) 2) constitute an important class of oxygen atom
transfer reagents in organic synthesis and are often used together with iron-based catalysts …

The development of catalysts capable of promoting CH hydroxylation reactions under mild
conditions holds tremendous promise for addressing socioeconomic challenges related to …

High-valent metal–oxo species have been characterised as key intermediates in both heme
and non-heme enzymes that are found to perform efficient aliphatic hydroxylation …